81664-99-5Relevant articles and documents
Synthesis of functionalized long-chain perfluoroalkanes from methyl halodifluoroacetates: a process of difluorocarbene insertion into copper-carbon bonds
Su, De-Bao,Duan, Jian-Xing,Yu, An-Juan,Chen, Qing-Yun
, p. 11 - 14 (2007/10/02)
Treatment of XCF2CO2Me (X = Cl, Br) with organic halides in the presence of KF and catalytic amounts of CuI at 80-120 deg C for 3-8 h in DMF gave long-chain perfluoroalkylated compounds which are considered to be former by the insertions of CF2(..) into carbon-copper bonds.
Reaction of Bis(heptafluorobutyryl) Peroxide with Carbanions and a Thiolate Anion
Yoshida, Masato,Shimokoshi, Kazuaki,Kobayashi, Michio
, p. 433 - 436 (2007/10/02)
In the reaction of bis(heptafluorobutyryl) peroxide with carbanions and a thiolate anion, two types of reactions were observed; one is an electron transfer reaction to give perfluoropropylated compounds and the other is a nucleophilic substitution.
PERFLUOROALKYLATION OF CARBANIONS
Umemoto, Teruo,Kuriu, Yuriko
, p. 5197 - 5200 (2007/10/02)
A successful perfluoroalkylation of various carbanions by the use of perfluoroalkylphenyliodonium trifluoromethanesulfonate (FITS) was described.The reactivity of other perfluoroalkyliodonium salt was also examined.