81665-29-4

Basic information

• Product Name: 1-{5-Hydroxy-2-[(triphenylsilanyl)-methyl]-2,3-dihydro-naphtho[1,2-b]furan-4-yl}-ethanone
• Synonyms: 1-{5-Hydroxy-2-[(triphenylsilanyl)-methyl]-2,3-dihydro-naphtho[1,2-b]furan-4-yl}-ethanone
• CAS NO: 81665-29-4
• Molecular Weight: 500.669
• Mol File: 81665-29-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-{5-Hydroxy-2-[(triphenylsilanyl)-methyl]-2,3-dihydro-naphtho[1,2-b]furan-4-yl}-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-{5-Hydroxy-2-[(triphenylsilanyl)-methyl]-2,3-dihydro-naphtho[1,2-b]furan-4-yl}-ethanone(81665-29-4)
• EPA Substance Registry System: 1-{5-Hydroxy-2-[(triphenylsilanyl)-methyl]-2,3-dihydro-naphtho[1,2-b]furan-4-yl}-ethanone(81665-29-4)

Safety Data

• Hazardous Substances Data: 81665-29-4(Hazardous Substances Data)

Upstream product

• 5813-57-0 2-acetyl-1,4-naphthoquinone 
• 18752-21-1 allyltriphenylsilane 

Downstream Products

• 81665-31-8 [4-(1-Bromo-ethyl)-5-methoxy-2,3-dihydro-naphtho[1,2-b]furan-2-ylmethyl]-triphenyl-silane 
• 81665-30-7 1-{5-Methoxy-2-[(triphenylsilanyl)-methyl]-2,3-dihydro-naphtho[1,2-b]furan-4-yl}-ethanol 

Relevant articles and documents

LEWIS ACID MEDIATED ALLYLATION OF 2-ALKANOYL-1,4-QUINONES WITH ALLYLSILANE AND ALLYLSTANNANE

Allyltrimethylstannane reacts with 2-alkanoyl-1,4-quinones regioselectively to afford conjugate addition products which can be derived to 2-alkanoyl-3-allylhydroquinone diacetate, while allyltriphenylsilane reacts with the quinone to give naphthofuran.