817598-79-1

Basic information

• Product Name: 4-biphenyl-4-yl-2-methylsulfanyl-pyrimidine
• Synonyms: 4-biphenyl-4-yl-2-methylsulfanyl-pyrimidine
• CAS NO: 817598-79-1
• Molecular Weight: 278.378
• Mol File: 817598-79-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-biphenyl-4-yl-2-methylsulfanyl-pyrimidine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-biphenyl-4-yl-2-methylsulfanyl-pyrimidine(817598-79-1)
• EPA Substance Registry System: 4-biphenyl-4-yl-2-methylsulfanyl-pyrimidine(817598-79-1)

Safety Data

• Hazardous Substances Data: 817598-79-1(Hazardous Substances Data)

Upstream product

• 823-09-6 2-(methylsulfanyl)pyrimidine 
• 1201-71-4 4-biphenyllithium 

Downstream Products

• 817598-91-7 4,6-bis-biphenyl-4-yl-2-methylsulfanyl-pyrimidine 

Relevant articles and documents

Pyrimidine-core extended π-systems: General synthesis and interesting fluorescent properties

We have developed a simple but powerful synthetic strategy that permits the assembly of π-systems onto a pyrimidine core in a programmable and diversity-oriented format. The nucleophilic addition of ArLi to 2-methylthiopyrimidine, followed by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation, resulted in the production of 4-aryl-2-methylthiopyrimidines. The iterative reaction sequence then gave 4,6-diaryl-2-methylthiopyrimidines. The resulting adduct was further allowed to react with ArMgBr under the catalytic influence of NiCl2(dppe) to afford 2,4,6-triarylpyrimidines. By following this synthetic scheme, interesting pyrimidine-core π-systems were rapidly constructed in a programmable fashion. The successful discovery of a number of interesting fluorescent materials and properties (e.g., solvatofluorochromism) speaks well for the potential of our platform strategy in the development of functional organic materials. Copyright