81846-56-2

Basic information

• Product Name: 3,6-anhydro-7-deoxy-7-nitro-L-glycero-L-galactoheptitol
• CAS NO: 81846-56-2
• Molecular Weight: 223.183
• Mol File: 81846-56-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,6-anhydro-7-deoxy-7-nitro-L-glycero-L-galactoheptitol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-anhydro-7-deoxy-7-nitro-L-glycero-L-galactoheptitol(81846-56-2)
• EPA Substance Registry System: 3,6-anhydro-7-deoxy-7-nitro-L-glycero-L-galactoheptitol(81846-56-2)

Safety Data

• Hazardous Substances Data: 81846-56-2(Hazardous Substances Data)

Upstream product

• 35800-09-0 7-deoxy-7-nitro-L-glycero-L-galactoheptitol hexaacetate 
• 16749-54-5 3,4,5,6,7-penta-O-acetyl-1,2-dideoxy-1-nitro-D-galacto-hept-1-enitol 
• 1299346-94-3 C₇H₁₃NO₇ 
• 75-52-5 nitromethane 
• 59-23-4 D-Galactose 

Relevant articles and documents

Preparation of D-galactofuranosyl nitromethanes: A revision and a new approach

Sodium methoxide-promoted methanolysis of 7-deoxy-7-nitro-l-glycero-l- galacto-heptitol peracetate rapidly and nearly quantitatively accumulates 7-deoxy-6-O-methyl-7-nitro-l-glycero-l-galacto-heptitol. The prolonged treatment then provides 76% of d-galactofuranosyl nitromethanes and finally results in the equilibrium of 77% of β-d-galactopyranosyl nitromethane and 7-9% of three other tautomeric d-galactosyl nitromethanes. Thermal treatment of 7-deoxy-7-nitro-l-glycero-l-galacto-heptitol in boiling water peaks at a 58% content of d-galactofuranosyl nitromethanes and ends in a similar equilibrium mixture of four d-galactosyl tautomers. The relevant kinetic parameters of the latter transformation are determined by a curve fitting using the nonlinear least-squares Marquardt-Levenberg algorithm.