81851-70-9Relevant articles and documents
Mechanisms in a Biomimetic Hydroxylation of a Chemical Probe: 5-Nitroacenaphthene
Khanna, Rajive K.,Sutherlin, Jody S.,Lindsey, David
, p. 6233 - 6234 (1990)
5-Nitroacenaphthene is hydroxylated by oxometalloporphyrin complexes of chromium, iron, and manganese via hydrogen atom abstraction pathways with charge separation in the transition state dependent on the electrophilicity of the oxygen atom in these model oxygenases.