82027-25-6

Basic information

• Product Name: (2-Hydroxy-adamantan-2-yl)-phenyl-methanone
• Synonyms: (2-Hydroxy-adamantan-2-yl)-phenyl-methanone
• CAS NO: 82027-25-6
• Molecular Weight: 256.345
• Mol File: 82027-25-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2-Hydroxy-adamantan-2-yl)-phenyl-methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Hydroxy-adamantan-2-yl)-phenyl-methanone(82027-25-6)
• EPA Substance Registry System: (2-Hydroxy-adamantan-2-yl)-phenyl-methanone(82027-25-6)

Safety Data

• Hazardous Substances Data: 82027-25-6(Hazardous Substances Data)

Upstream product

• 123844-15-5 [4-(Adamantan-2-ylidene-phenyl-methoxy)-phenoxy]-tert-butyl-dimethyl-silane 
• 201151-81-7 2-(2-Hydroxy-adamantan-2-yl)-2-phenyl-benzo[1,3]dioxol-5-ol 
• 132959-20-7 α-(trimethylsiloxy)-2-adamantanyl phenyl ketone 
• 113849-79-9 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane 
• 700-58-3 2-Adamantanone 
• 31675-43-1 diethyl 1-phenyl-1-(trimethylsiloxy)methanephosphonate 
• 201151-77-1 C₂₉H₃₈O₄Si 

Downstream Products

• 82027-14-3 2-benzoyl-2-adamantyl mesylate 
• 700-58-3 2-Adamantanone 

Relevant articles and documents

F--induced decomposition of 3-[(tert-Butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetanes without C-C bond cleavage of the dioxetane ring

F--induced decomposition of 3-[3-tert-butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetane (5c) yielded an intramolecular redox product (7b), whereas 3-phenoxy-3-(3-siloxyphenyl)-1,2-dioxetane (3) gave normal carbonyl fragments with intense light emission. An isomer (5a) gave light with normal decomposition by CIEEL, though the major process was one to yield an acyloin (7a).

OXIDATIONS BY METHYL TRIFLUOROMETHYL DIOXIRANE. EPOXIDATION OF ENOL ETHERS

Isolated methyl trifluoromethyl dioxirane 4b has been employed to achieve the rapid, low temperature epoxidation of enol ethers, such as alkoxy(aryl)methylidene adamantanes 1a-e and methoxy(2-naphtyl)methylidene 2-bornane 1f, affording the corresponding spirooxiranes in excellent (92-97percent) yields.