82112-98-9

Basic information

• Product Name: chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)
• Synonyms: chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)
• CAS NO: 82112-98-9
• Molecular Weight: 333.169
• Mol File: 82112-98-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)(82112-98-9)
• EPA Substance Registry System: chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)(82112-98-9)

Safety Data

• Hazardous Substances Data: 82112-98-9(Hazardous Substances Data)

Upstream product

• 474888-54-5 [Au(C₆H₃(CH₂NMe₂)2-2,6)(triphenylphosphine)] 
• 27199-13-9 bis(diethyl sulfide)palladium dichloride 
• 15617-18-2 bis(benzonitrile)palladium(II) dichloride 
• 115338-66-4 rhodium{C₆H₃(CH₂NMe₂)2-o,o'}(1,5-cyclooctadiene) 

Downstream Products

• 797057-61-5 benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) 
• 695221-33-1 μ-chlorobis[2,6-bis((dimethylamino)methyl)phenylpalladium(II)]tetrakis[4-(trimethylsilyl)phenyl]borate 

Relevant articles and documents

A bis(ortho-amine)aryl-gold(I) compound as an efficient, nontoxic, arylating reagent

A novel strategy for the synthesis of bis(ortho-amine)chelated monoanionic bisaminoaryl-metal complexes is presented. This method constitutes the exchange of a monoanionic, NCN-pincer ligand (NCN = [C6H3(CH2NMe2)2-2,6] -) between a stable arylgold(I) phosphine, [Au(η1-C-NCN)(PPh3)] (2), and a transition metal halide. This transmetalation results in the quantitative formation of[M(NCN)] organometallic compounds (M = AuIII, NiII, PdII, PtII, TiIV, and FeIII) and [AuCl(PPh3)] as the only coproduct that can be recovered.