82141-12-6Relevant articles and documents
Hydrazinolysis of (E)- and (Z)-2-Phenyl-3-Phenylethenyl-1-Phthalimidoaziridines
Belov,Blandov,Kuznetsov
, p. 641 - 646 (2007/10/03)
Hydrazinolysis of stereoisomeric trans-2-phenyl-3-[(E)- and (Z)-phenylethenyl]-1-phthalimidoaziridines proceeds stereospecifically and yields not the expected 1-amino-2-phenyl-3-phenylethenylaziridines but isomeric 1-amino-2,5-diphenyl-3-pyrrolines. Oxidation of the latter with lead tetraacetate is also stereo-specific, and it results in formation of stereoisomeric 1,4-diphenylbutadienes. Hydrazinolysis of (E)-phthalimidoaziridines under milder conditions yields a product of incomplete removal of the phthaloyl group, whose oxidation affords cis-1,4-dihydro-1,4-diphenylpyridazino[1,2-b]phthalazine-6,11-dione.