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82145-67-3

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82145-67-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 82145-67-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,1,4 and 5 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 82145-67:
(7*8)+(6*2)+(5*1)+(4*4)+(3*5)+(2*6)+(1*7)=123
123 % 10 = 3
So 82145-67-3 is a valid CAS Registry Number.

82145-67-3Downstream Products

82145-67-3Relevant articles and documents

Enantioselective borohydride reduction catalyzed by optically active cobalt complexes

Yamada, Tohru,Nagata, Takushi,Sugi, Kiyoaki D.,Yorozu, Kiyotaka,Ikeno, Taketo,Ohtsuka, Yuhki,Miyazaki, Daichi,Mukaiyama, Teruaki

, p. 4485 - 4509 (2007/10/03)

The highly enantioselective borohydride reduction of aromatic ketones or imines to the corresponding alcohols was developed in the presence of a catalytic amount of an optically active cobalt(II) complex catalyst. This enantioselective reduction is carried out using a precisely premodified borohydride with alcohols such as tetrahydrofurfuryl alcohol, ethanol and methanol. High optical yields are obtained by choosing the appropriate alcohol as modifiers and a suitable β-ketoiminato ligand of the catalyst. The enantioselective borohydride reduction has been successfully applied to the preparation of optically active 1,3-diols, the stereoselective reduction of diacylferrocenes, and dynamic and/or kinetic resolution of 1,3-dicarbonyl compounds.

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