82158-43-8Relevant articles and documents
Copper(I)-Catalyzed Chemoselective Reduction of Benzofuran-2-yl Ketones to Alcohols with B2pin2 via a Domino-Borylation-Protodeboronation Strategy
Xuan, Qingqing,Kong, Weiguang,Song, Qiuling
, p. 7602 - 7607 (2017)
A novel copper(I)-catalyzed chemoselective reduction of the carbonyls of benzofuran-2-yl ketones over furan rings with B2pin2 has been developed. This reaction proceeded under mild conditions. High valuable secondary alcohol derivatives of benzofurans were obtained in good to excellent yields with a broad substrate scope. The mechanistic studies suggested that a domino-borylation-protodeboronation pathway was involved in this reaction.
Condensation Product of Salicylaldehyde and 2-Bromo-2'-hydroxyacetophenone: Revision of Structure
Joshi, U. K.,Paradkar, M. V.
, p. 378 - 379 (2007/10/02)
Reaction between salicylaldehyde and 2-bromo-2'-hydroxyacetophenone (1) gives 2-(2-hydroxybenzylidene)coumaran-3-one (5) rather than 2-(2-hydroxybenzoyl)benzofuran (2) as reported in a patented literature.