821788-48-1

Basic information

• Product Name: (1R,4aR,8aS)-decahydronaphthalen-1-ol
• CAS NO: 821788-48-1
• Molecular Weight: 154.252
• Mol File: 821788-48-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,4aR,8aS)-decahydronaphthalen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4aR,8aS)-decahydronaphthalen-1-ol(821788-48-1)
• EPA Substance Registry System: (1R,4aR,8aS)-decahydronaphthalen-1-ol(821788-48-1)

Safety Data

• Hazardous Substances Data: 821788-48-1(Hazardous Substances Data)

Upstream product

• 935-31-9 (Z)-cyclodecene 
• 821788-45-8 (1R,4S,4aR,8aS)-4-hydroxy-decahydronaphthalen-1-yl acetate 
• 821788-44-7 (1R,4S,4aR,8aS)-4-hydroxy-1,2,3,4,4a,8,8a-octahydronaphthalen-1-yl acetate 
• 85737-81-1 (1R,4S,4aR,8aS)-4-(acetoxy)-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-yl acetate 
• 92372-70-8 (1R,4S,4aR,8aS)-4-(acetoxy)-decahydronaphthalen-1-yl acetate 
• 1127-50-0 (1R,4S,4aR,8aS)-decahydronaphthalene-1,4-diol 
• 63950-11-8 1α,4α-dihydroxy-cis-1,2,3,4,4a,5,8,8a-octahydronaphthalene 
• 821788-47-0 (1R,8aS)-1,2,3,4,5,6,7,8,8a-octahydronaphthalen-1-ol 
• 29587-92-6 cis-1,2-epoxy-cyclodecane 
• 821788-46-9 (1R,4S,4aR,8aS)-4-[(methylsulfonyl)oxy]-decahydronaphthalen-1-yl acetate 

Relevant articles and documents

Enzymatic desymmetrization of meso-1α,4α-dihydroxy-cis-decalins

The stereoselective acetylation of meso-decalindiols 1 and 2 by vinyl acetate in the presence of Candida antarctica lipase gave monoester (1R,4S,4aR,8aS)-5 and (1R,4S,4aR,8aS)-6 in high enantiomeric excess (ee ≥98%). The hydrolysis of the corresponding meso-diacetates 3 and 4 in the presence of porcine liver esterase in phosphate buffer provided the opposite enantiomers.

Enantioselective α-deprotonation-rearrangement of meso-epoxides

Enantioselective α-deprotonation-rearrangement of medium-sized (8-, 9- and 10-membered) cycloalkene-derived meso-epoxides using organolithiums in the presence of (-)-sparteine gives bicyclic alcohols in good yields and ees.