823-94-9

Basic information

• Product Name: 2,4,6-trimethyl-1,3,5-triazine
• Synonyms: 2,4,6-trimethyl-1,3,5-triazine;1,3,5-Triazine, 2,4,6-trimethyl-
• CAS NO: 823-94-9
• Molecular Formula: C₆H₉N₃
• Molecular Weight: 123.1558
• EINECS: 200-258-5
• Mol File: 823-94-9.mol
• Article Data: 9

Chemical Properties

• Melting Point: 59-60 °C
• Boiling Point: 289.3°Cat760mmHg
• Flash Point: 137°C
• Appearance: /
• Density: 1.044g/cm³
• Vapor Pressure: 0.00386mmHg at 25°C
• Refractive Index: 1.505
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 3.41±0.10(Predicted)
• CAS DataBase Reference: 2,4,6-trimethyl-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-trimethyl-1,3,5-triazine(823-94-9)
• EPA Substance Registry System: 2,4,6-trimethyl-1,3,5-triazine(823-94-9)

Safety Data

• Hazardous Substances Data: 823-94-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H9N3/c1-4-7-5(2)9-6(3)8-4/h1-3H3

Upstream product

• 67-56-1 methanol 
• 6313-33-3 formamidine hydrochloride 
• 143-37-3 acetamidine 
• 75-05-8 acetonitrile 
• 598-25-4 Dimethylallene 
• 616-05-7 2-bromohexanoic acid 
• 7417-48-3 3-methyl-1,2-pentadiene 
• 7664-41-7 ammonia 
• 1493-13-6 trifluorormethanesulfonic acid 
• 613-92-3 N-hydroxybenzenecarboximidamide 
• 5373-87-5 4-methoxybenzamidoxime 
• 192332-48-2 N'-hydroxy-4-nitrobenzimidamide 

Downstream Products

• 461-98-3 4-amino-2,6-dimethylpyrimidine 
• 87019-98-5 2,4,6-tris[(E)-2-phenylethenyl]-1,3,5-triazine 
• 4413-30-3 N,N'-diphenyl-C-methylformazan 
• 30362-01-7 tris-dibromomethyl s-triazine 
• 33721-00-5 N-(2,6-dimethylpyrimidin-4-yl)acetamide 
• 138606-48-1 1-(4,6-dimethyl-s-triazin-2-yl)prop-1-en-2-ol 
• 7559-34-4 2,4-dimethyl-6-propyl-s-triazine 
• 30362-06-2 2,4-dimethyl-6-(2-methylpropyl)-s-triazine 
• 30361-98-9 2-Brommethyl-4,6-dimethyl-s-triazin 
• 615266-53-0 2,4,6-tris[(E)-2-(4-methylphenyl)ethenyl]-1,3,5-triazine 

Relevant articles and documents

Reaction of amidoximes with acetonitrile at high pressure

Reaction of amidoximes with acetonitrile giving 1,2,4-oxadiazoles occurs at 80-100 °C under a pressure of 10 Kbar without catalysts.

Electrophilic fluorination

N-fluorotriazinium salts, especially those of the following Formula I, are electrophilic fluorinating agents useful in fluorinating, preferably in a nitromethane solvent, carbanionic species and/or activated aromatic compounds:wherein three A moieties are independently CR, where each R is, independently, hydrogen, halogen, (primary, secondary or tertiary) amino, hydroxyl, amino, cyano, perfluorothio hydroxysulphonyl, halosulphonyl, hydrocarbyloxysulphonyl,, or a carbon-containing substituent selected from optionally substituted hydrocarbyl, hydrocarbyloxy, hydrocarbyloxycarbonyl, and hydrocarbylthio groups; two A moieties are independently Z, where each Z is independently nitrogen or a quaternary nitrogen atom and Y is a counterion or group of counterions which are inert to chemical attack by fluorine, and oligomers or polymers thereof in which adjacent triazinium moieties are linked by a common R substituent. Preferably the cation of the salt is 2,4,6-trichloro-1,3,5-triazinium.

Electrophilic fluorination

N-fluorotriazinium salts, especially those of the following Formula I, are electrophilic fluorinating agents useful in fluorinating, preferably in a nitromethane solvent, carbanionic species and/or activated aromatic compounds: wherein three A moieties are independently CR, where each R is, independently, hydrogen, halogen, (primary, secondary or tertiary) amino, hydroxyl, amino, cyano, perfluorothio hydroxysulfonyl, halosulfonyl, hydrocarbyloxysulfonyl, or a carbon-containing substituent selected from the group consisting of optionally substituted hydrocarbyl, hydrocarbyloxy, hydrocarbyloxycarbonyl, and hydrocarbylthio groups; two A moieties are independently Z, where each Z is independently nitrogen or a quaternary nitrogen atom and Y is a counterion or group of counterions which are inert to chemical attack by fluorine, and oligomers or polymers thereof in which adjacent triazinium moieties are linked by a common R substituent. Preferably the cation of the salt is 2,4,6-trichloro-1,3,5-triazinium.