82360-62-1

Basic information

• Product Name: O-(4'-Chlorobenzoyl)-N,N-dimethylbenzamidoxime
• CAS NO: 82360-62-1
• Molecular Weight: 302.76
• Mol File: 82360-62-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: O-(4'-Chlorobenzoyl)-N,N-dimethylbenzamidoxime(CAS DataBase Reference)
• NIST Chemistry Reference: O-(4'-Chlorobenzoyl)-N,N-dimethylbenzamidoxime(82360-62-1)
• EPA Substance Registry System: O-(4'-Chlorobenzoyl)-N,N-dimethylbenzamidoxime(82360-62-1)

Safety Data

• Hazardous Substances Data: 82360-62-1(Hazardous Substances Data)

Upstream product

• 65986-63-2 (E)-N,N-Dimethylbenzamid-oxim 
• 122-01-0 4-chloro-benzoyl chloride 
• 932-90-1 Benzaldoxime 
• 698-16-8 benzohydroximoyl chloride 

Relevant articles and documents

CONFIGURATION AND CONFORMATION OF AMIDOXIMES. N,N-DIALKYL DERIVATIVES

Dipole moments of N,N-dialkylamidoximes Ia-Ie and of substituted O-benzoyl-N,N-dimethylbenzamidoximes IIa-IIe were measured in benzene or dioxan, respectively.The results with the later set of compounds allow to assign in an independent and unambiguous way the E-configuration which was found previously for all N,N-dialkylamidoximes investigated in the crystalline state; our reasoning does not involve bond moment values within the amidoxime functional group.The fundamental difference in the stereochemistry between unsubstituted amidoximes and their N,N-dialkyl derivatives has been confirmed.On the other hand, the configuration of simple N,N-dialkylamidoximes (e.g.Ia-Ie) cannot be deduced from their dipole moments in a straightforward manner.The reason is that the conjugation within the N=C-N chain requires a mesomeric correction term which cannot be neglected and is not equal in either configuration.The example shows very clearly limitations of the bond moment approach if applied to conjugated molecules.