82395-76-4Relevant articles and documents
STABLE CARBOCATIONS FROM TERPENOIDS. IV. GENERATION OF STABLE IONS FROM SOME MONOTERPENES OF THE MENTAHNE AND CARANE SERIES
Popova, L. A.,Bardyshev, I. I.,Korchagina, D. V.,Dubovenko, Zh. V,Gatilov, Yu. V.,Barkhash, V. A.
, p. 709 - 720 (2007/10/02)
Stable carbocations were generated for the first time from momoterpenes of the menthane and carane-dipentene series, terpinolene, α and γ-terpinenes, isomeric p-menthenes, cis- and trans-caranes, and silvestrene.Their structures, reactions with nucleophiles, and certain rearrangements were studied.Differences were noted in the reactivity of the substrates in superacids and under conditions of acid catalysis