824-59-9Relevant articles and documents
Solvent-free chelation-assisted catalytic C-C bond cleavage of unstrained ketone by rhodium(I) complexes under microwave irradiation
Ahn, Jeong-Ae,Chang, Duck-Ho,Young, Jun Park,Ye, Rim Yon,Loupy, Andre,Jun, Chul-Ho
, p. 55 - 58 (2007/10/03)
A highly efficient C-C bond cleavage of unstrained aliphatic ketones bearing β-hydrogens with olefins was achieved using a chelation-assisted catalytic system consisting of (Ph3P)3RhCl and 2-amino-3-picoline by microwave irradiation under solvent-free conditions. The addition of cyclohexylamine catalyst accelerated the reaction rate dramatically under microwave irradiation compared with the classical heating method.
Palladium-catalyzed norbornene-carbon monoxide co-oligomerization initiated by aryl groups and terminated by double bond formation
Dalcanale, E.,An, Z.,Battaglia, L. P.,Catellani, M.,Chiusoli, G. P.
, p. 375 - 388 (2007/10/02)
The use of m-iodophenol as initiator in palladium-catalyzed norbornene-carbon monoxide oligomerization in the presence of potassium acetate unexpectedly leads to termination by double bond formation in spite of the limitations to β-H-anti elimination.The presence of endo products points to preliminary exo-to-endo isomerization through enolization.The X-ray structure of one stereoisomer (Ia) is given.
COMPARATIVE INVESTIGATION OF THE STEREO- AND REGIOSELECTIVITY OF THE HYDROALUMINATION OF OLEFINS OF NORBORNANE STRUCTURE WITH VARIOUS REAGENTS
Kuchin, A. V.,Nurushev, R. A.,Khalilov, L. M.,Tolstikov, G. A.
, p. 1574 - 1579 (2007/10/02)
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