82456-65-3

Basic information

• Product Name: chromium⁽⁰⁾ hexakis(2,6-dimethylphenyl isocyanide)
• Synonyms: chromium⁽⁰⁾ hexakis(2,6-dimethylphenyl isocyanide)
• CAS NO: 82456-65-3
• Molecular Weight: 839.059
• Mol File: 82456-65-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: chromium⁽⁰⁾ hexakis(2,6-dimethylphenyl isocyanide)(CAS DataBase Reference)
• NIST Chemistry Reference: chromium⁽⁰⁾ hexakis(2,6-dimethylphenyl isocyanide)(82456-65-3)
• EPA Substance Registry System: chromium⁽⁰⁾ hexakis(2,6-dimethylphenyl isocyanide)(82456-65-3)

Safety Data

• Hazardous Substances Data: 82456-65-3(Hazardous Substances Data)

Upstream product

• 10170-68-0 trichlorotris(tetrahydrofuran)chromium(III) 
• 119072-54-7 2,6-dimethylphenyl isonitrile 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 

Downstream Products

• 85135-18-8 Cr(2,6-dimethylphenyl isocyanide)6BF₄ 

Relevant articles and documents

STUDIES ON THE INTERACTION OF ISOCYANIDES WITH TRANSITION METAL COMPLEXES. XXVII. PREPARATION OF ZEROVALENT ISOCYANIDE COMPLEXES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN. THE CRYSTAL STRUCTURE OF HEXAKIS(2,6-XYLYLISOCYANIDE)MOLYBDENUM CONTAINING BENZENE AS A SOLVATED MOLECULE

Hexakis(isocyanide)metals, M(RNC)6 (M=Cr, Mo, W; R=2,6-Me2C6H4, 2,4,6-Me3C6H2, 2,4-t-Bu2-6-MeC6H2, 2,4,6,-t-Bu3C6H2 and t-Bu), were prepared by the reduction of a halide of chromium(III), molybdenum(IV), molybdenum(V) or tungsten(VI) with sodium amalgam in the presence of an isocyanide.An X-ray crystallographic study of Mo(2,6-Me2C2H3NC)6*C6H6 revealed that the molybdenum atom is approximately octahedrally coordinated by six isocyanide ligands.