82495-54-3

Basic information

• Product Name: (E)-5-(tert-Butyl-diphenyl-silanyloxy)-1-imidazol-1-yl-3-methyl-pent-2-en-1-one
• CAS NO: 82495-54-3
• Molecular Weight: 418.611
• Mol File: 82495-54-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-5-(tert-Butyl-diphenyl-silanyloxy)-1-imidazol-1-yl-3-methyl-pent-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-5-(tert-Butyl-diphenyl-silanyloxy)-1-imidazol-1-yl-3-methyl-pent-2-en-1-one(82495-54-3)
• EPA Substance Registry System: (E)-5-(tert-Butyl-diphenyl-silanyloxy)-1-imidazol-1-yl-3-methyl-pent-2-en-1-one(82495-54-3)

Safety Data

• Hazardous Substances Data: 82495-54-3(Hazardous Substances Data)

Upstream product

• 19710-84-0 5-hydroxy-3-methyl-2-(E)-pentenoic acid 
• 35066-36-5 5-hydroxy-3-methyl-2-(E)-pentenoic acid methyl ester 
• 82495-51-0 (2E)-5-(tert-butyldiphenylsilyloxy)-3-methylpent-2-enoic acid 
• 530-62-1 1,1'-carbonyldiimidazole 

Downstream Products

• 76685-82-0 trichoverrin B 
• 82521-42-4 C₅₇H₈₆O₉Si₃ 

Relevant articles and documents

Synthesis of Trichoverrin B and Its Conversion to Verrucarin J

Anguidine (3b) was converted to verrucarol (3a), which in turn was selectively acylated to yield trichoverin B (2).Trichoverrin B reacts with pyridinium dichromate in dimethylformamide, via a novel oxidative ring closure, to give verrucarin J (11a) in 50 percent yield.