82517-80-4

Basic information

• Product Name: Spiro[bicyclo[3.1.0]hex-3-ene-2,2-[1,3]dioxolane], 6-methylene-
• CAS NO: 82517-80-4
• Molecular Formula: C9H10O2
• Molecular Weight: 0
• Mol File: 82517-80-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Spiro[bicyclo[3.1.0]hex-3-ene-2,2-[1,3]dioxolane], 6-methylene-(CAS DataBase Reference)
• NIST Chemistry Reference: Spiro[bicyclo[3.1.0]hex-3-ene-2,2-[1,3]dioxolane], 6-methylene-(82517-80-4)
• EPA Substance Registry System: Spiro[bicyclo[3.1.0]hex-3-ene-2,2-[1,3]dioxolane], 6-methylene-(82517-80-4)

Safety Data

• Hazardous Substances Data: 82517-80-4(Hazardous Substances Data)

Upstream product

• 71946-88-8 C₉H₁₂BrClO₂ 

Relevant articles and documents

NON-KEKULE MOLECULES DERIVED CONCEPTUALLY BY HETEROATOM-FOR-CARBON SUBSTITUTION IN ALTERNANT HYDROCARBONS; M-QUINOMETHANE AND M-NAPHTHOQUINOMETHANE

Qualitative theoretical considerations suggest that substitution of a heteroatom for a C atom in an alternant hydrocarbon might result in a non-Kekule molecule with a triplet ground state, despite the non-degeneracy of the Hueckel NBMOs of the heteroatom derivative.The syntheses of 3-methylene-1-phenoxyl and 3-methylene-1-naphthoxyl are described.These compounds, biradical valence tautomers of m-quinomethanes, are characterized by EPR spectroscopy and are assigned triplet ground states.Optical resolution of 6-methylene-bicyclohex-3-ene-2-one, the precursor of 3-methylene-1-phenoxyl, is described.Repeated irradiation of the active ketone at 20K with intermittent warming to room temperature followed by re-isolation gives ketone of undiminished activity, which suggests that re-cyclization of (presumably achiral) 3-methylene-1-phenoxyl does not occur under these conditions.