82572-27-8

Basic information

• Product Name: Ethanone, 2-methoxy-1,2-diphenyl-, (2S)-
• CAS NO: 82572-27-8
• Molecular Formula: C15H14O2
• Molecular Weight: 226.275
• Mol File: 82572-27-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-methoxy-1,2-diphenyl-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-methoxy-1,2-diphenyl-, (2S)-(82572-27-8)
• EPA Substance Registry System: Ethanone, 2-methoxy-1,2-diphenyl-, (2S)-(82572-27-8)

Safety Data

• Hazardous Substances Data: 82572-27-8(Hazardous Substances Data)

Upstream product

• 3524-62-7 benzoin monomethyl ether 
• 33993-53-2 N,S-dimethyl-S-phenylsulfoximine 
• 118298-90-1 Trifluoro-acetic acid (S)-2-oxo-1,2-diphenyl-ethyl ester 
• 451-40-1 phenyl benzyl ketone 
• 5928-67-6 (S)-(+)-benzoin 
• 74-88-4 methyl iodide 

Downstream Products

• 118353-44-9 (+)-erythro-α,β-diphenyl-β-hydroxyethanol methyl ether 

Relevant articles and documents

HPLC enantioseparation on a homochiral MOF-silica composite as a novel chiral stationary phase

The last frontier in the development of chiral stationary phases for chromatographic enantioseparation involves homochiral metal-organic frameworks (MOFs). Using enantiopure (R)-2,2′-dihydroxy-1,1′-binaphthalene-6,6′-dicarboxylic acid as a starting material, we prepared three homochiral MOFs that were further used as chiral stationary phases for high-performance liquid chromatography to separate the enantiomers of various kinds of racemic sulfoxides, sec-alcohols, β-lactams, benzoins, flavanones and epoxides. The experimental results showed excellent performances for enantioseparation, and highlighted that enantioseparation on homochiral MOF columns is practical.

NEW CHIRAL STATIONARY PHASES FOR CHROMATOGRAPHY BASED ON AROMATIC ALLYL AMINES

New chiral stationary phases (CSPs) based on chiral selectors covalently bound on a solid support were prepared. Chiral selectors were obtained from enantiomerically pure aromatic amines and 3,5-dinitrobenzoic acid and then linked to the support surface through the allylic double bond. Such obtained materials allow enantioseparation of racemates or enantiomerically enriched compounds. These chiral stationary phases can be used as fillings in chromatographic columns for enantiomer separation of naproxen type drugs and other similar non-steroidal anti-inflammatory drugs (NSAID) by means of high performance liquid chromatography on both the analytical and preparative scale.

Flash Chiral Chromatography using Carbohydrate Carbamate-coated Silica

Enantiomers of many chiral compounds are resolved rapidly on a preparative scale by passage through a column packed with flash chromatography silica which has been physically coated with a carbohydrate carbamate.