82637-15-8

Basic information

• Product Name: (S)-N-(1-phenylethyl)diphenylphosphinamide
• Synonyms: (S)-N-(1-phenylethyl)diphenylphosphinamide
• CAS NO: 82637-15-8
• Molecular Weight: 321.359
• Mol File: 82637-15-8.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: (S)-N-(1-phenylethyl)diphenylphosphinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-(1-phenylethyl)diphenylphosphinamide(82637-15-8)
• EPA Substance Registry System: (S)-N-(1-phenylethyl)diphenylphosphinamide(82637-15-8)

Safety Data

• Hazardous Substances Data: 82637-15-8(Hazardous Substances Data)

Upstream product

• 544-97-8 dimethyl zinc(II) 
• 98837-46-8 N-benzylidenediphenylphosphinamide 
• 82572-06-3 P,P-diphenyl-N-(1-phenylethylidene)phosphinic amide 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 1079-66-9 chloro-diphenylphosphine 
• 82944-84-1 N-[(1E)-1-phenylethylidene]-P,P-diphenylphosphinic amide 
• 1499-21-4 Diphenylphosphinic chloride 
• 98-86-2 acetophenone 
• 613-91-2 acetophenone oxime 
• 5994-87-6 diphenylphosphinamide 
• 10341-75-0 (E)-1-phenylethanone oxime 
• 98837-46-8 P,P-diphenyl-N-(phenylmethylene)phosphinic amide 
• 75-24-1 trimethylaluminum 
• 71554-93-3 (S)-(-)-N-diphenylphosphino-α-methylbenzylamine 

Downstream Products

• 2627-86-3 (S)-1-phenyl-ethylamine 
• 874280-81-6 diphenylphosphinic acid N-methyl-(S)-α-methylbenzylamide 
• 1010128-68-3 N-benzyl-P,P-diphenyl-N-[(1S)-1-phenylethyl]phosphinic amide 
• 223505-12-2 (1R,3R,4S)-2-<(1S)-phenylethyl>-2-aza-bicyclo<2.2.1>hept-5-ene-3-carboxylic acid ethyl ester 

Relevant articles and documents

Zirconium complexes having a chiral phosphanylamide in the co-ordination sphere

The chiral phosphanylamido ligand, {N(CHMePh)(PPh2)} -, has been introduced into co-ordination chemistry. As starting material the oily amines HN(R-*CHMePh)(PPh2) (1a) and HN(S-*CHMePh)(PPh2) (1b) were used. To

Asymmetric Transfer Hydrogenation in Thermomorphic Microemulsions Based on Ionic Liquids

A thermomorphic ionic-liquid-based microemulsion system was successfully applied for the Ru-catalyzed asymmetric transfer hydrogenation of ketones. On the basis of the temperature-dependent multiphase behavior of the targeted microemulsion, simple product separation as well as catalyst recycling could be realized. The use of water-soluble ligands improved the immobilization of the catalyst in the microemulsion phase and significantly decreased the catalyst leaching into the organic layer upon extraction of the product. Eventually, the optimized microemulsion system could be applied to a wide range of aromatic ketones that were reduced with good isolated yields (up to 98%) and enantioselectivities (up to 97%), while aliphatic ketones were less successful.

A New Phosphine-Amine-Oxazoline Ligand for Ru-Catalyzed Asymmetric Hydrogenation of N-Phosphinylimines

A series of chiral phosphine-amine-oxazoline (PAO) ligands with an NH moiety were synthesized and applied to the ruthenium-catalyzed asymmetric hydrogenation of N-phosphinylimines. The ligand bearing phenyl groups at the phosphorus moiety and isopropyl at the oxazoline moiety exhibits good activity and excellent enantioselectivity (up to 99% ee). This catalytic system provides an efficient and mild approach to access enantioriched amines.