82679-48-9Relevant articles and documents
Selectivity in the Allylic Substitutions with Organometallics through Neighboring Coordination. 2-(Allyloxy)benzothiazoles as SN2' Electrophiles for Regio- and Stereoselective Olefin Syntheses
Calo, Vincenzo,Lopez, Luigi,Pesce, Giannangelo,Calianno, Antonia
, p. 4482 - 4485 (2007/10/02)
An efficient control of the regio- and stereochemistry in the allylic substitutions with organomagnesium compounds has been achieved by using 2-(allyloxy)benzothiazoles as substrates in the presence of copper bromide.The selectivity is due to the coordinative effects of the substrates toward the organometallic species.