82730-81-2

Basic information

• Product Name: Ethanone, 1-(6,6-dimethylbicyclo[3.1.0]hex-2-en-3-yl)-, (1R-cis)- (9CI)
• Synonyms: Ethanone, 1-(6,6-dimethylbicyclo[3.1.0]hex-2-en-3-yl)-, (1R-cis)- (9CI)
• CAS NO: 82730-81-2
• Molecular Formula: C10H14O
• Molecular Weight: 150.21756
• Product Categories: ACETYLGROUP
• Mol File: 82730-81-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(6,6-dimethylbicyclo[3.1.0]hex-2-en-3-yl)-, (1R-cis)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(6,6-dimethylbicyclo[3.1.0]hex-2-en-3-yl)-, (1R-cis)- (9CI)(82730-81-2)
• EPA Substance Registry System: Ethanone, 1-(6,6-dimethylbicyclo[3.1.0]hex-2-en-3-yl)-, (1R-cis)- (9CI)(82730-81-2)

Safety Data

• Hazardous Substances Data: 82730-81-2(Hazardous Substances Data)

Upstream product

• 82730-80-1 (-)-cis-3-(3-oxobutyl)-2,2-dimethylcyclopropanecarboxaldehyde 
• 65878-59-3 Δ²-(+)-carene 

Relevant articles and documents

Preparation, Stereochemistry, and Nuclear Magnetic Resonance Spectroscopy of 4-Hydroxy(acetoxy)bicyclooctanes. Synthesis of (-)- and (+/-)-8,8-Dimethylbicyclooct-2-en-4-one

A potentially versatile intermediate for the synthesis of natural products containing the bicyclooctane ring system is 8,8-dimethylbicyclooct-2-en-4-one (1).This intermediate was prepared efficiently in racemic form from 5-acetoxycycloheptene and in chiral form (1R,7S) from (-)-2-carene, via separate synthetic strategies.In addition, a number of 4-hydroxy(acetoxy)bicyclooctanes (3, 4, and 6) were also prepared and their stereochemistry established rigorously by NMR spectroscopy and chemical correlation to 3t, the structure of which was determined by X-ray crystallographic analysis.