82751-22-2

Basic information

• Product Name: diethyl phenylsulfanyl(phenyl)malonate
• Synonyms: diethyl phenylsulfanyl(phenyl)malonate
• CAS NO: 82751-22-2
• Molecular Weight: 344.431
• Mol File: 82751-22-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: diethyl phenylsulfanyl(phenyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl phenylsulfanyl(phenyl)malonate(82751-22-2)
• EPA Substance Registry System: diethyl phenylsulfanyl(phenyl)malonate(82751-22-2)

Safety Data

• Hazardous Substances Data: 82751-22-2(Hazardous Substances Data)

Upstream product

• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 83-13-6 diethyl 2-phenylmalonate 
• 101-97-3 Ethyl 2-phenylethanoate 
• 2949-92-0 methanethiosulfonic acid S-methyl ester 

Downstream Products

• 10490-07-0 2-phenyl-2-(phenylthio)acetic acid 

Relevant articles and documents

A novel and easy de-ethoxycarbonylation of α-substituted malonic esters

The reaction of some α-substituted malonic esters with Triton B in DMSO to give the corresponding α-substituted carboxylic esters is reported.

A Convenient Method for Preparation of 2-(Methylthio)alkanoic Acids and Their Related Compounds Using the Carbanions of Substituted Malonic Esters

Starting from alkyl- or aryl-substituted malonic esters prepared by various methods, 2-(methylthio)alkanoic acids are synthesized by successive treatment with sodium ethoxide and with S-methyl methanethiosulfonate, followed by alkaline hydrolysis which causes concurrent decarboxylation.Production of 2-(phenylthio)alkanoic acids is also achieved in a similar manner.