82884-05-7

Basic information

• Product Name: Carbonic acid 2,6-dimethyl-phenyl ester 2-nitro-phenyl ester
• CAS NO: 82884-05-7
• Molecular Weight: 287.272
• Mol File: 82884-05-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbonic acid 2,6-dimethyl-phenyl ester 2-nitro-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid 2,6-dimethyl-phenyl ester 2-nitro-phenyl ester(82884-05-7)
• EPA Substance Registry System: Carbonic acid 2,6-dimethyl-phenyl ester 2-nitro-phenyl ester(82884-05-7)

Safety Data

• Hazardous Substances Data: 82884-05-7(Hazardous Substances Data)

Upstream product

• 576-26-1 2.6-dimethylphenol 
• 81420-42-0 mononitrophenyl carbonate 

Relevant articles and documents

NOVEL CATALYSIS OF o-NITROPHENYL CARBONATES BY p-DIMETHYLAMINOPYRIDINE

Transesterification reactions of o-nitrophenyl carbonates have been found to be greatly facilitated by use of p-dialkylaminopyridines as catalysts.A 20-fold rate increase is observed using 0.01 eq. of p-dimethylaminopyridine in place of 2.00 eq. of triethylamine.Such rate enhancement is not observed with p-nitrophenyl carbonates: 2.00 eq. of Et3N causes reaction to occur 8.5 times faster than 0.01 eq. of DMAP.DMAP catalyzed reactions of o-nitrophenyl carbonate have been used to prepare aromatic carbonates at 0 deg C in high yields, and avoid the necessity of using 2 equiv. of base.