82907-01-5

Basic information

• Product Name: Benzene, 1-chloro-4-(trifluoroethenyl)-
• CAS NO: 82907-01-5
• Molecular Formula: C8H4ClF3
• Molecular Weight: 192.568
• Mol File: 82907-01-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(trifluoroethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(trifluoroethenyl)-(82907-01-5)
• EPA Substance Registry System: Benzene, 1-chloro-4-(trifluoroethenyl)-(82907-01-5)

Safety Data

• Hazardous Substances Data: 82907-01-5(Hazardous Substances Data)

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 105417-08-1 trifluoroethenylzinc bromide 
• 79-38-9 Chlorotrifluoroethylene 
• 116-14-3 polytetrafluoroethylene 
• 35692-30-9 (4-chlorophenyl)trimethoxysilane 
• 827605-29-8 2-(4-chloro-phenyl)-5,5-dimethyl-[1,3,2]dioxaborinane 
• 51833-36-4 4-chlorophenylmagnesium chloride 
• 72487-06-0 1-(4-chlorophenyl)-2,2,2-trifluoroethanol 
• 811-97-2 1,1,1,2-tetrafluoroethane 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 1679-18-1 4-Chlorophenylboronic acid 

Relevant articles and documents

The method of manufacturing the same and hydroxybenzenes (trifluorolactic vinyl)

PROBLEM TO BE SOLVED: To provide (trifluorovinyl)benzenes and a method for producing the same.SOLUTION: The method for producing (trifluorovinyl)benzenes expressed by general formula (3) comprises carrying out a reaction of a phenyl boron compound with trifluorohaloethylenes in the coexistence of 1 to 100 equivalents of water with respect to the phenyl boron compound (1), a palladium complex coordinated with a bidentate phosphine ligand, and an alkali metal salt. In formula (3), Rrepresents a hydrogen atom or a formyl group; Rand Reach independently represents a hydrogen atom, 1-4C alkyl group, 2-4C alkenyl group, 2-5C acyl group, (1-4C alkoxy)carbonyl group, 1-4C alkoxy group, tri(1-4C alkyl)silyl group, 2-5C acylamino group, cyano group, phenyl group, chlorine atom, fluorine atom or nitro group; and adjoining Rand Rmay form a ring together with a carbon atom bonded thereto.

Palladium-catalyzed base-free Suzuki-Miyaura coupling reactions of fluorinated alkenes and arenes via a palladium fluoride key intermediate

A new strategy for C-C bond formation with organoboronates through C-F activation of fluorinated alkenes and arenes was developed. In this Pd-catalyzed Suzuki-Miyaura-type cross-coupling reaction, neither a base for enhancing the reactivity of the organoboron reagents nor a Lewis acid for promoting C-F bond activation was required. A fluoropalladium intermediate played an essential role in this reaction. In addition, a Ni(NHC) catalyst was efficient for C-C coupling through C-F bond activation of fluoroarenes. Pd0/PR 3 complexes promote C-C bond formation with organoboronates through C-F bond activation of fluorinated alkenes. Mechanistic studies show that a PdII fluoride intermediate plays an essential role in this base-free cross-coupling reaction. Moreover, a Ni(NHC) catalyst is efficient for C-C coupling through C-F bond cleavage of fluoroarenes. Copyright

Pd-catalyzed arylation of chlorotrifluoroethylene using arylboronic acids

The palladium-catalyzed cross-coupling of chlorotrifluoroethylene and arylboronic acids proceeds in the presence of a base and H2O to provide α,β,β-trifluorostyrene derivatives in satisfactory yields.