82925-88-0

Basic information

• Product Name: 1,1,1-TRIS(CHLOROMETHYL)PROPANE
• Synonyms: 1,1,1-TRIS(CHLOROMETHYL)PROPANE;1 1 1-TRIS(CHLOROMETHYL)PROPANE 99%
• CAS NO: 82925-88-0
• Molecular Formula: C₆H₁₁Cl₃
• Molecular Weight: 189.51
• Mol File: 82925-88-0.mol
• Article Data: 6

Chemical Properties

• Melting Point: 42-44 °C(lit.)
• Flash Point: 207 °F
• Appearance: /
• CAS DataBase Reference: 1,1,1-TRIS(CHLOROMETHYL)PROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-TRIS(CHLOROMETHYL)PROPANE(82925-88-0)
• EPA Substance Registry System: 1,1,1-TRIS(CHLOROMETHYL)PROPANE(82925-88-0)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 82925-88-0(Hazardous Substances Data)

Usage

Synonyms

Tris(chloromethyl)propane

Physical state

Colorless, oily liquid

Uses

a. Crosslinking agent in epoxy resins
b. Monomer in polymer synthesis
c. Building block for pharmaceuticals and agrochemicals

Toxicity

Highly toxic

Hazards

a. Skin irritation
b. Eye irritation
c. Respiratory system irritation

Safety measures

Proper handling and storage required to minimize exposure and potential harm.

Upstream product

• 77-99-6 1,1,1-tri(hydroxymethyl)propane 
• 98-59-9 p-toluenesulfonyl chloride 
• 82925-87-9 5-chloromethyl-5-ethyl-2-thia-1,3-dioxane 2-oxide 

Downstream Products

• 101069-25-4 1,1,1-tris(diphenylphosphinomethyl)propane 
• 941697-84-3 C₆₃H₅₉N₁₀P₃ 
• 941697-86-5 C₆₃H₅₆N₁₀P₃Br₃ 

Relevant articles and documents

A flexible, convergent approach to polycyclic indole structures: Formal synthesis of (±)-mersicarpine

The formal synthesis of (±)-mersicarpine was achieved using an lntermolecular radical addition-radical cyclization cascade. This key reaction represents a flexible, convergent route to numerous polycyclic indole derivatives.

New trigonal tris(phosphine oxides)

The reaction of 1,1,1-tris(chloromethyl)propane with diphenylphosphine under phase-transfer conditions afforded 1,1,1-tris(diphenylphosphinomethyl) propane, whose oxidation gave a previously unknown representative of trigonal tris(phosphine oxides), viz.,

PRODUCTION OF CYCLIC SULFITES AND THEIR TRANSFORMATION INTO SUBSTITUTED TRI(CHLOROMETHYL)METHANES

The production of cyclic sulfites from trihydric alcohols and their conversion into chlorides by the action of DMFA-SOCl2 complex are described.By PMR and IR spectroscopy it was shown that cyclic sulfites exist preferentially in the chair conformation with the axial orientation of the S=O bond.It was established that the chlorides are formed in two parallel paths, i.e. directly from trihydric alcohols and their cyclic sulfites.