82929-69-9

Basic information

• Product Name: 3-{2-[(Z)-1-Phenyl-ethylimino]-cyclohexyl}-propionic acid methyl ester
• Synonyms: 3-{2-[(Z)-1-Phenyl-ethylimino]-cyclohexyl}-propionic acid methyl ester
• CAS NO: 82929-69-9
• Molecular Weight: 287.402
• Mol File: 82929-69-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-{2-[(Z)-1-Phenyl-ethylimino]-cyclohexyl}-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-{2-[(Z)-1-Phenyl-ethylimino]-cyclohexyl}-propionic acid methyl ester(82929-69-9)
• EPA Substance Registry System: 3-{2-[(Z)-1-Phenyl-ethylimino]-cyclohexyl}-propionic acid methyl ester(82929-69-9)

Safety Data

• Hazardous Substances Data: 82929-69-9(Hazardous Substances Data)

Upstream product

• 292638-85-8 acrylic acid methyl ester 
• 10407-33-7 methyl 3-(2-oxocyclohexyl)propionate 
• 618-36-0 rac-methylbenzylamine 

Relevant articles and documents

REACTIVITE COMPAREE DES ISOMERES IMINE ET ENAMINE SILICIES: SYNTHESE ENANTIOSELECTIVE DE L'(OXO-2 CYCLOHEXYL)-3 PROPIONATE DE METHYLE

The isomerisation process between SiMe3-substituted enamines and imines (N-SiC-Si) is so slow that each isomer is able to react independently.The silicon-substituted (S)-phenylethylamine derivative adds to methyl acrylate and forms, upon hydrolysis, methyl (S)-3-(2-oxocyclohexyl)propane carboxylate.The tautomeric imine leads to the (R)-enantiomer.Surprisingly, in the presence of a Lewis acid, the ring-containing organosilicon-substituted derivatives show lower stereoselectivity than the corresponding tin compounds.