83074-76-4

Basic information

• Product Name: (1,2-Hexadienyl)(p-tolyl)sulfoxid
• Synonyms: (1,2-Hexadienyl)(p-tolyl)sulfoxid
• CAS NO: 83074-76-4
• Molecular Weight: 220.335
• Mol File: 83074-76-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1,2-Hexadienyl)(p-tolyl)sulfoxid(CAS DataBase Reference)
• NIST Chemistry Reference: (1,2-Hexadienyl)(p-tolyl)sulfoxid(83074-76-4)
• EPA Substance Registry System: (1,2-Hexadienyl)(p-tolyl)sulfoxid(83074-76-4)

Safety Data

• Hazardous Substances Data: 83074-76-4(Hazardous Substances Data)

Upstream product

• 933-00-6 p-methylbenzenesulfenyl chloride 
• 105-31-7 1-hexyn-3-ol 

Downstream Products

• 83074-89-9 1-(p-Tolylsulfinyl)-2-hexanon 
• 83074-83-3 (2-Diethylamino-1-hexen-1-yl)(p-tolyl)sulfoxid 

Relevant articles and documents

Phosphorus- and Sulfur-substituted Allenes in Synthesis, III. - β-Keto Sulfoxides from 3-Alkyn-1-ols via Allenic Sulfoxides

Allenic sulfoxides 3, readily available by sigmatropic rearrangement of sulfenic esters 2 of 3-alkyn-1-ols 1, can be transformed to give β-keto sulfoxides 9 by nucleophilic addition of diethylamine and subsequent hydrolysis of the formed enamines.