831235-57-5

Basic information

• Product Name: [Pd(2,4,6-trifluorophenyl)(C₆H₄-4-OMe)(N,N,N',N'-tetramethylethylenediamine)]
• CAS NO: 831235-57-5
• Molecular Weight: 460.836
• Mol File: 831235-57-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(2,4,6-trifluorophenyl)(C₆H₄-4-OMe)(N,N,N',N'-tetramethylethylenediamine)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(2,4,6-trifluorophenyl)(C₆H₄-4-OMe)(N,N,N',N'-tetramethylethylenediamine)](831235-57-5)
• EPA Substance Registry System: [Pd(2,4,6-trifluorophenyl)(C₆H₄-4-OMe)(N,N,N',N'-tetramethylethylenediamine)](831235-57-5)

Safety Data

• Hazardous Substances Data: 831235-57-5(Hazardous Substances Data)

Upstream product

• 191667-15-9 (N,N,N',N'-tetramethylethylenediamine)Pd(I)(C₆H₄OMe-p) 
• 182482-25-3 2,4,6-trifluorophenylboronic acid 

Relevant articles and documents

Diarylpalladium complexes with a cis structure. Formation via transmetalation of arylboronic acids with an aryliodopalladium complex and intramolecular coupling of the aryl ligands, affording unsymmetrical biaryls

(2,4,6-Trifluorophenyl)- and (2,6-difluoropheny)boronic acids react with PdI(C6H4O-4-Me)(tmen) (tmen = N,N,N',N'- tetramethylethylenediamine) in the presence of Ag2O to produce cis-diarylpalladium complexes with a tmen ligand via intermolecular transfer of the fluorophenyl group from B to Pd. The isolated complexes undergo coupling of the two aryl ligands upon heating the solution to 45-60 °C to afford unsymmetrical biaryls.