83167-57-1Relevant articles and documents
Stereoselective Synthesis of 1-O-Alkyl-3-O-benzyl-sn-glycerols and 1-O-Alkyl-2-O-methyl-3-O-β-D-glycosyl-sn-glycerols
Bauer, Friederike,Ruess, Klaus-Peter,Lieflaender, Manfred
, p. 765 - 768 (2007/10/02)
Starting with D-mannitol, the yield of th synthesis of 3-O-benzyl-sn-glycerol (1) could be improved.The regioselective alkylation of 1 at the primary hydroxy group to the 1-O-alkyl-3-O-benzyl-sn-glycerols 3 was achieved by using the dibutylstannylene protecting group.The 1-O-alkyl-2-O-methyl-sn-glycerols 4, readily obtainable from 3, were successfully glycosylated under the conditions of the Koenigs-Knorr reaction to give 1-O-alkyl-2-O-methyl-3-O-β-D-glycosyl-sn-glycerols. - Key Words: Lysoglycolipids, glyceryl ethers / Stereoselective synthesis / Koenigs-Knorr reaction / Glyceryl ethers
Selective formation of chiral glycerol ethers: a synthesis of intermediates of a platelet-activating factor (C19-PAF)
Takano,Akiyama,Ogasawara
, p. 791 - 794 (2007/10/02)
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