83182-25-6Relevant articles and documents
Cycloelimination of β-Silylethyl Sulphoxides: Alkene, Alkyne, and Vinylsilane-forming Reactions
Fleming, Ian,Goldhill, Jon,Perry, David A.
, p. 1563 - 1570 (2007/10/02)
The cycloelimination (1)->(3) of trimethylsilyl sulphenate from a β-silylethyl sulphoxide is slightly faster than the corresponding cycloelimination (2)->(3) of sulphenic acid itself.The former type of reaction can be used to form acetylenes (