832-97-3Relevant articles and documents
Biocontrolled formal inversion or retention of L -α-amino acids to enantiopure (R)- or (S)-hydroxyacids
Busto, Eduardo,Grischek, Barbara,Kroutil, Wolfgang,Richter, Nina
supporting information, p. 11225 - 11228,4 (2015/01/07)
Natural L-α-amino acids and L-norleucine were transformed to the corresponding α-hydroxy acids by formal biocatalytic inversion or retention of absolute configuration. The one-pot transformation was achieved by a concurrent oxidation reduction cascade in aqueous media. A representative panel of enantiopure (R)- and (S)-2-hydroxy acids possessing aliphatic, aromatic and heteroaromatic moieties were isolated in high yield (67-85 %) and enantiopure form (>99 % ee) without requiring chromatographic purification.
Preparation of 3-(3-indolyl)lactic acids. A new synthesis of rac-blepharismone, the low molecular conjugation gamone of Blepharisma japonicum
Entzeroth,Kunczik,Jaenicke
, p. 226 - 230 (2007/10/02)
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