833460-51-8

Basic information

• Product Name: Silane, trimethyl[1-(methylthio)-2-phenylethenyl]-
• Synonyms: Silane,trimethyl[1-(methylthio)-2-phenylethenyl]
• CAS NO: 833460-51-8
• Molecular Formula: C12H18SSi
• Molecular Weight: 222.42200
• Mol File: 833460-51-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[1-(methylthio)-2-phenylethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[1-(methylthio)-2-phenylethenyl]-(833460-51-8)
• EPA Substance Registry System: Silane, trimethyl[1-(methylthio)-2-phenylethenyl]-(833460-51-8)

Safety Data

• Hazardous Substances Data: 833460-51-8(Hazardous Substances Data)

Upstream product

• 10428-57-6 trimethyl[(methylthio)methyl]silane 
• 100-52-7 benzaldehyde 
• 833460-47-2 methylthio(tert-butyldimethylsilyl)trimethylsilyl-methane 

Downstream Products

• 56583-94-9 (phenylacetyl)trimethylsilane 

Relevant articles and documents

Evaluation of C-trialkylsilyl enol and thioenol ethers as intermediates in the synthesis of acylsilanes

C-silyl enol ethers or thioenol ethers have been prepared by a Peterson reaction, as intermediates for acylsilane synthesis. Bis(trialkylsilyl)(methoxy) - or -(methylsulfanyl)methanes bearing identical or different trialkylsilyl groups were used as starting materials in order to assess the selectivity of the Peterson elimination step. A good selectivity was observed only with ethers bearing the TMS and TBDMS groups. However, there is no practical interest to use such reagents owing to the difficulty to obtain them in correct yields. Bis(trimethylsilyl)(methylsulfanyl)methane proved to be a good reagent for the preparation of C-silyl thioenol ethers, which are hydrolyzed under classical acid conditions to give acylsilanes in fair overall yields. This convenient procedure was extended to the synthesis of bis(acylsilanes). Graphical Abstract.