83347-24-4

Basic information

• Product Name: Fe(((C₆H₅)2P(O)CH₂CH₂)2)(ONO₂)3
• CAS NO: 83347-24-4
• Molecular Weight: 700.338
• Mol File: 83347-24-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Fe(((C₆H₅)2P(O)CH₂CH₂)2)(ONO₂)3(CAS DataBase Reference)
• NIST Chemistry Reference: Fe(((C₆H₅)2P(O)CH₂CH₂)2)(ONO₂)3(83347-24-4)
• EPA Substance Registry System: Fe(((C₆H₅)2P(O)CH₂CH₂)2)(ONO₂)3(83347-24-4)

Safety Data

• Hazardous Substances Data: 83347-24-4(Hazardous Substances Data)

Upstream product

• 7782-61-8 ferric nitrate 
• 4151-27-3 1,4-bis(diphenylphosphinyl)butane 

Relevant articles and documents

Chemistry of Iron Complexes. Part 1. Synthesis, Characterization, and Structures of Iron(3+) Complexes with Bis(tertiary phosphine oxides)

Bidentate bis(tertiary phosphine oxides) (L-L) such as PP'-methylene- (mdpo), PP'-ethylene- (edpo), PP'-tetramethylene- (tmdpo), and PP'-hexamethylene-bis(diphenylphosphine oxides) (hmdpo) on reaction with iron(3+) chloride or nitrate in suitable organic solvents yield complexes of the types: *xH2O (x = 0 for all except hmdpo), (L-L = tmdpo or hmdpo), *H2O (L-L = edpo), and 2*2H2O (L-L = mdpo).These complexes have been characterized by elemental analyses, i.r., far-i.r., u.v.-visible, e.s.r., and Moessbauer spectral data, molar conductance, thermogravimetric analysis, magnetic moments, and X-ray diffraction data.The cation (1+) has been assigned a trans-octahedral structure.The nitrate complex of mdpo has a dimeric trigonal bipyramidal cation while the complex of edpo has a cis-octahedral structure.The nitrate complexes of tmdpo and hmdpo also have trigonal bipyramidal structure.