83548-12-3

Basic information

• Product Name: ((1S,2S)-2-Nitro-cyclohexylselanyl)-benzene
• Synonyms: ((1S,2S)-2-Nitro-cyclohexylselanyl)-benzene
• CAS NO: 83548-12-3
• Molecular Weight: 284.217
• Mol File: 83548-12-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ((1S,2S)-2-Nitro-cyclohexylselanyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((1S,2S)-2-Nitro-cyclohexylselanyl)-benzene(83548-12-3)
• EPA Substance Registry System: ((1S,2S)-2-Nitro-cyclohexylselanyl)-benzene(83548-12-3)

Safety Data

• Hazardous Substances Data: 83548-12-3(Hazardous Substances Data)

Upstream product

• 34837-55-3 Phenylselenyl bromide 
• 110-83-8 cyclohexene 
• 1666-13-3 diphenyl diselenide 
• 2562-37-0 1-nitrocyclohexene 

Downstream Products

• 1402812-20-7 C₁₉H₁₇NO 
• 1402812-83-2 C₂₅H₂₅NO₃ 
• 2562-37-0 1-nitrocyclohexene 

Relevant articles and documents

Preparation and rearrangement of N-vinyl nitrones: Synthesis of spiroisoxazolines and fluorene-tethered isoxazoles

N-Vinyl nitrones derived from fluorenone have been prepared via a copper-mediated coupling between fluorenone oxime and vinyl boronic acids. These compounds undergo subsequent rearrangement and addition reactions that are distinct from the traditional [3 + 2] cycloaddition reactivity of nitrones. Thermal rearrangements of fluorenone N-vinyl nitrones give spiroisoxazolines, while treatment with alkynes provides fluorene-tethered isoxazoles. The scope and limitations of the preparation of fluorenone N-vinyl nitrones and their subsequent rearrangement and addition reactions are discussed.

SYNTHESIS OF 2-NITROALKYL PHENYL SELENIDES AND THEIR CONVERSION TO NITROALKENES

Treatment of alkenes with benzeneselenenyl bromide followed by addition of silver nitrite provided a mixture of 2-nitroalkyl and 2-hydroxyalkyl phenyl selenides.Oxidation of the former selenides with hydrogen peroxide gave nitroalkenes in 90-93 percent yields.