83614-06-6Relevant articles and documents
Carbon-Nitrogen and Nitrogen-Nitrogen Bond Formation from Nucleophilic Attack at Coordinated Nitrosyls in Fe and Ru Heme Models
Abucayon, Erwin G.,Powell, Douglas R.,Richter-Addo, George B.
supporting information, p. 9495 - 9498 (2017/07/24)
The conversion of inorganic NOx species to organo-N compounds is an important component of the global N-cycle. Reaction of a C-based nucleophile, namely the phenyl anion, with the ferric heme nitrosyl [(OEP)Fe(NO)(5-MeIm)]+ generates a mixture of the C-nitroso derivative (OEP)Fe(PhNO)(5-MeIm) and (OEP)Fe(Ph). The related reaction with [(OEP)Ru(NO)(5-MeIm)]+ generates the (OEP)Ru(PhNO)(5-MeIm) product. Reactions with the N-based nucleophile diethylamide results in the formation of free diethylnitrosamine, whereas the reaction with azide results in N2O formation; these products derive from attack of the nucleophiles on the bound NO groups. These results provide the first demonstrations of C-N and N-N bond formation from attack of C-based and N-based nucleophiles on synthetic ferric-NO hemes.
SYNTHESES AND MAGNETIC PROPERTIES OF ARYLIRON(III) COMPLEXES OF OCTAETHYLPORPHYRINS
Ogoshi, Hisanobu,Sugimoto, Hiroshi,Yoshida, Zen-Ichi,Kabayashi, Hanako,Sakai, Hiroshi,Maeda, Yutaka
, p. 185 - 196 (2007/10/02)
Aryliron(III) octaethylporphyrins, OEP-FeIII(4-XC6H4) were obtained from octaethylporphyrinatoiron(III) perchlorate, OEP-FeIII(ClO4) and arylmagnesium bromides.In order to confirm the ESR parameters, the
