83739-62-2Relevant articles and documents
Electrochemical Alkoxyhalogenation of Alkenes with Organohalides as the Halide Sources via Dehalogenation
Li, Jin-Heng,Li, Yang,Luo, Mu-Jia,Song, Ren-Jie,Zhang, Ting-Ting
supporting information, p. 7250 - 7254 (2020/10/05)
A general, ideal atom utilization electrochemical technology to enable alkene alkoxyhalogenation and organohalide dehalogenation in one pot is presented. This technology is highlighted by convergent strategy integrating several reactions, such as alkene alkoxyhalogenation, organohalide dehalogenation, and dehalogenation deuteration. Experimental data suggest that alkenes have the lowest oxidation potential, which lead to anodic conversion of the C═C bond to the radical cation intermediates, and cathodic transformations of organohalides, including alkyl and aryl halides, as the nucleophilic halogen sources.
Alkoxybromination of olefins using ammonium bromide and oxone
Kumar, Macharla Arun,Naresh, Mameda,Rohitha, Chozhiyath Nappunni,Narender, Nama
supporting information, p. 3121 - 3129 (2014/01/06)
A mild, efficient, and highly regio- and stereoselective method for the methoxy and ethoxy bromination of olefins has been developed using NH 4Br as a bromine source and Oxone as an oxidant. Various kinds of olefins (aromatic, linear, and cyclic olefins) afforded the corresponding alkoxy brominated products in moderate to excellent yields. Taylor & Francis Group, LLC.
SYNTHESE, EIGENSCHAFTEN UND CARBONYL-INSERTIONS-REAKTIONEN VON TETRACARBONYLEISEN(0)-KOMPLEXEN para-SUBSTITUIERTER STYROLE
Schmidt, Eckhart K.G.,Dogan, Mehmet
, p. 73 - 84 (2007/10/02)
The Fe(CO)4 η2-complexes of para-substituted styrenes (substituent=H, CH3, OCH3, Cl, F) can be obtained in good yields.Complexation changes drastically the chemical shifts and coupling constants of the vinyl protons.Reaction of the complexes wi
