83766-52-3Relevant articles and documents
Highly Site-Selective Formation of Perfluoroalkylated Anilids via a Protecting Strategy by Molybdenum Hexacarbonyl Catalyst
Yuan, Chunchen,Dai, Ping,Bao, Xiaoguang,Zhao, Yingsheng
supporting information, p. 6481 - 6484 (2019/08/20)
Introducing a perfluoroalkyl group on the aromatic ring with high site selectivity remains a challenging area in organofluorine chemistry. We herein report a highly para-selective C-H perfluoroalkylation of aniline substrates using the molybdenum hexacarbonyl catalyst. Various substituted anilids derived from anilids were well-tolerated, affording the corresponding products in moderate to good yields. Preliminary mechanism studies and density functional theory calculations revealed the coordination of Mo catalyst with amides as the key factor to realize para selectivity.
Facile fabrication of multifunctional perfluoroalkyl functionalized graphene hydrogel via a synchronous reduction and grafting strategy
Li, Ting,Ding, Yunqiao,Liu, Libin,Liu, Jian,Fang, Wenyuan,Xiang, Yu,Li, Tianduo
, p. 21744 - 21753 (2015/11/10)
Fluorine-containing groups represent very promising functionalities because fluorine not only changes the physico-chemical properties of the graphene surface, it may also alter its electronic and magnetic properties. Herein, we describe, for the first tim
Synthesis and characterization of photoresponsive POSS-based polymers and their switchable water and oil wettability on cotton fabric
Huang, Jianbao,Huang, Yangen,He, Chuanglong,Gao, Yu
, p. 100339 - 100346 (2015/12/04)
Fast photoresponsive polymers containing polyhedral oligomeric silsesquioxane (POSS) and fluorinated azobenzene groups were successfully prepared via radical polymerization and characterized by NMR, FTIR, XRD, GPC, TGA, etc. The photoresponsive properties of the polymers were investigated through ultraviolet-visible absorption spectra. The trans-cis photoisomerization of the polymers in solution conformed to a first-order reaction kinetics equation. Superhydrophobicity and high oleophobicity of the cotton fabric coated with the polymer was observed when the POSS mole ratio was 3.0%. More importantly, the surface wettability of both water and oil on the coated fabrics could be intelligently controlled by applying UV irradiation in a short time.