84039-67-8Relevant articles and documents
Double carbonylation of aryl iodides with diethylamine catalyzed by dinuclear palladium complexes
Tsukada, Naofumi,Ohba, Yoichi,Inoue, Yoshio
, p. 436 - 443 (2003)
Dinuclear palladium complexes bridged by a novel PNNP ligand, N,N ′-bis[(2-diphenylphosphino)phenylformamidinate (dpfam), were found to be very efficient and selective catalysts for the double carbonylation of iodobenzene with diethylamine using K3PO4 as base and 1,4-dioxane as solvent with a TON up to 105 and selectivity of 96%.
CATALYTIC DOUBLE CARBONYLATION OF ORGANOHALOGEN COMPOUNDS PROMOTED BY PALLADIUM COMPLEXES
Ozawa, Fumiyuki,Soyama, Hidehiko,Yamamoto, Takakazu,Yamamoto, Akio
, p. 3383 - 3386 (2007/10/02)
Various organohalogen compounds can be catalytically converted into α-keto amides on reaction with carbon monoxide and amines.Tertiary phosphine-coordinated palladium compounds are particularly suitable as the double carbonylation catalyst.