84065-86-1

Basic information

• Product Name: 3-Azetidinecarbonitrile, 3-(1,1-dimethylethyl)-2-(4-methoxyphenyl)-1-methyl-4-thioxo-
• CAS NO: 84065-86-1
• Molecular Formula: C16H20N2OS
• Molecular Weight: 288.414
• Mol File: 84065-86-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Azetidinecarbonitrile, 3-(1,1-dimethylethyl)-2-(4-methoxyphenyl)-1-methyl-4-thioxo-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Azetidinecarbonitrile, 3-(1,1-dimethylethyl)-2-(4-methoxyphenyl)-1-methyl-4-thioxo-(84065-86-1)
• EPA Substance Registry System: 3-Azetidinecarbonitrile, 3-(1,1-dimethylethyl)-2-(4-methoxyphenyl)-1-methyl-4-thioxo-(84065-86-1)

Safety Data

• Hazardous Substances Data: 84065-86-1(Hazardous Substances Data)

Upstream product

• 91529-47-4 3,3-Dimethyl-2-(4-oxo-1,3-dithietan-2-yliden)butyronitril 
• 42867-44-7 2-(Dichlormethylen)-3,3-dimethylbutyronitril 
• 113354-25-9 (Z)-2-(1,3-Dithiolan-2-yliden)-3,3-dimethylbutannitril-S-oxid 
• 91529-41-8 2-(1,3-Dithiolan-2-yliden)-3,3-dimethylbutyronitril 
• 91529-64-5 2-<5,6-Dihydro-4-(4-methoxyphenyl)-5-methyl-6-oxo-4H-1,3,5-dithiazin-2-yliden>-3,3-dimethylbutyronitril 
• 113378-74-8 (Z)-2-(1,3-Dithiolan-2-yliden)-3,3-dimethylbutannitril-S,S-oxid 
• 13114-23-3 4-methoxybenzyl-N-methylimine 

Relevant articles and documents

Thioketene Syntheses, VIII. - Thioketenes by Cycloreversion of 1,3-Dithiolane Derivatives

2-Alkylidene-1,3-dithiolanes are transformed into S,S-dioxides 1 and S-ethyl- 2 or S-arylsulfonium salts 3.After deprotonation at C-5 they form in a cycloreversion thioketenes 5, which can be trapped as thioamides 17, 18.The stabilized thioketenes 5e,i-k afford 1:1 cycloadducts 24a, b, 27a-d with azomethines; in addition, thioketene 5j provides a dimer 28j, which was characterized by an X-ray structural investigation.