84076-81-3

Basic information

• Product Name: {(1,2-bis(diphenylphosphino)ethane)Au2}(μ-2,2'-bibenzimidazolato)
• CAS NO: 84076-81-3
• Molecular Weight: 1024.6
• Mol File: 84076-81-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(1,2-bis(diphenylphosphino)ethane)Au2}(μ-2,2'-bibenzimidazolato)(CAS DataBase Reference)
• NIST Chemistry Reference: {(1,2-bis(diphenylphosphino)ethane)Au2}(μ-2,2'-bibenzimidazolato)(84076-81-3)
• EPA Substance Registry System: {(1,2-bis(diphenylphosphino)ethane)Au2}(μ-2,2'-bibenzimidazolato)(84076-81-3)

Safety Data

• Hazardous Substances Data: 84076-81-3(Hazardous Substances Data)

Upstream product

• 18024-34-5 1,2-bis(diphenylphosphino)ethane digold(I) dichloride 
• 6965-02-2 2,2'-bi-1H-benzimidazole 

Downstream Products

• 85530-03-6 [(((C₆H₅)2PCH₂)2)Au₂(C₁₄H₈N₄)Rh(C₈H₁₂)]⁽¹⁺⁾*ClO₄^(1-)=[(((C₆H₅)2PCH₂)2)Au₂(C₁₄H₈N₄)Rh(C₈H₁₂)]ClO₄ 
• 85539-01-1 [(((C₆H₅)2PCH₂)2)Au₂(C₁₄H₈N₄)Rh(CO)(P(C₆H₅)3)]⁽¹⁺⁾*ClO₄^(1-)=[(((C₆H₅)2PCH₂)2)Au₂(C₁₄H₈N₄)Rh(CO)(P(C₆H₅)3)]ClO₄ 
• 85530-09-2 [(((C₆H₅)2PCH₂)2)Au₂(C₁₄H₈N₄)Rh(CO)2]⁽¹⁺⁾*ClO₄^(1-)=[(((C₆H₅)2PCH₂)2)Au₂(C₁₄H₈N₄)Rh(CO)2]ClO₄ 

Relevant articles and documents

Mononuclear gold(I) and heteronuclear gold(I)-palladium(II) bibenzimidazolate complexes with new coordination modes of the ligand

Metathetic reactions of gold(I) halide complexes and the potassium salt of 2,2′-bibenzimidazol afford binuclear bibenzimidazolate gold(I) complexes with the general formula {Au2L2}(μ-BiBzIm) L = PPh3, PBun3, P(OMe)3; L2 = 1,1-bis(diphenylphosphine)-methane (dppm), 1,2-bis(diphenylphosphine)ethane (dppe). These complexes are Lewis bases and can be used as precursors for the synthesis of tri and tetranuclear cationic gold(I) complexes, or trinuclear gold(I) and palladium(II) complexes where the bibenzimidazolate anion is acting as bridging tetranuclear ligand. An hexanuclear gold(I)-palladium(II) complex is also described.