84145-52-8

Basic information

• Product Name: 6-oxo-3-methylhexyl acetate
• Synonyms: 6-oxo-3-methylhexyl acetate;6-(Acetyloxy)-4-methylhexanal;Einecs 282-279-0
• CAS NO: 84145-52-8
• Molecular Formula: C9H16O3
• Molecular Weight: 172.22154
• EINECS: 282-279-0
• Mol File: 84145-52-8.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 238.1°C at 760 mmHg
• Flash Point: 96.8°C
• Appearance: /
• Density: 0.966g/cm³
• Vapor Pressure: 0.0431mmHg at 25°C
• Refractive Index: 1.425
• CAS DataBase Reference: 6-oxo-3-methylhexyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 6-oxo-3-methylhexyl acetate(84145-52-8)
• EPA Substance Registry System: 6-oxo-3-methylhexyl acetate(84145-52-8)

Safety Data

• Hazardous Substances Data: 84145-52-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H16O3/c1-8(4-3-6-10)5-7-12-9(2)11/h6,8H,3-5,7H2,1-2H3

Upstream product

• 20425-54-1 (R)-1-citronellyl acetate 
• 1564-98-3 (3R)-5-(3,3-dimethyloxiran-2-yl)-3-methylpentan-1-ol 
• 1117-61-9 (3R)-citronellol 
• 18951-85-4 (R)-citronellic acid 
• 1147880-35-0 (R)-citronallol acetate oxide 
• 150-84-5 citronellyl-acetate 
• 106-22-9 Citronellol 
• 67601-05-2 (3S)-3,7-dimethyl-6-octen-1-yl acetate 
• 2436-90-0 (S)-(+)-dihydromyrcene 
• 7540-51-4 (S)-3,7-dimethyl-6-octen-1-ol 
• 1787-98-0 (3S)-3,7-dimethyl-6,7-epoxyoctan-1-yl acetate 
• 26759-58-0 Acetic acid (S)-6,7-dihydroxy-3,7-dimethyl-octyl ester 

Relevant articles and documents

LUMINALLY-ACTING N-(PIPERIDIN-4-YL)BENZAMIDE DERIVATIVES

Disclosed are compounds of Formula 1, and pharmaceutically acceptable salts thereof, wherein m, R1, R2, R3, R4, R5, R6, X1, X2, X3 and X4 are defined in the specification. This disclosure also relates to materials and methods for preparing compounds of Formula 1, to pharmaceutical compositions which contain them, and to their use for treating diseases, disorders, and conditions associated with the 5-HT4 receptor.

Surfactant-Assisted Ozonolysis of Alkenes in Water: Mitigation of Frothing Using Coolade as a Low-Foaming Surfactant

Aqueous-phase ozonolysis in the atmosphere is an important process during cloud and fog formation. Water in the atmosphere acts as both a reaction medium and a reductant during the ozonolysis. Inspired by the atmospheric aqueous-phase ozonolysis, we herein report the ozonolysis of alkenes in water assisted by surfactants. Several types of surfactants, including anionic, cationic, and nonionic surfactants, were investigated. Although most surfactants enhanced the solubility of alkenes in water, they also generated excessive foaming during the ozone bubbling, which led to the loss of products. Mitigation of the frothing was accomplished by using Coolade as a nonionic and low-foaming surfactant. Coolade-assisted ozonolysis of alkenes in water provided the desired carbonyl products in good yields and comparable to those achieved in organic solvents. During the ozonolysis reaction, water molecules trapped within the polyethylene glycol region of Coolade were proposed to intercept the Criegee intermediate to provide a hydroxy hydroperoxide intermediate. Decomposition of the hydroxy hydroperoxide led to formation of the carbonyl product without the need for a reductant typically required for the conventional ozonolysis using organic solvents. This study presents Coolade as an effective surfactant to improve the solubility of alkenes while mitigating frothing during the ozonolysis in water.

Synthesis of all the stereoisomers of 6-methyl-2-octadecanone, 6,14-dimethyl-2-octadecanone, and 14-methyl-2-octadecanone, the components of the female-produced sex pheromone of a moth, Lyclene dharma dharma

All of the stereoisomers of the components of the female-produced sex pheromone of a moth, Lyclene dharma dharma, were synthesized. They are (R)- and (S)-6-methyl-2-octadecanone, (6R,14R)-, (6R,14S)-, (6S,14R)-, and (6S,14S)-6,14-dimethyl-2-octadecanone, and (R)- and (S)-14-methyl-2-octadecanone. Enantiomers of citronellal and methyl (S)-3-hydroxy-2-methylpropanoate were the starting materials, and olefin cross metathesis was employed as the key reaction.