84181-11-3

Basic information

• Product Name: (CH₃C₆H₄CC₄NH₂)4MnOCH₃
• CAS NO: 84181-11-3
• Molecular Weight: 754.813
• Mol File: 84181-11-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃C₆H₄CC₄NH₂)4MnOCH₃(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃C₆H₄CC₄NH₂)4MnOCH₃(84181-11-3)
• EPA Substance Registry System: (CH₃C₆H₄CC₄NH₂)4MnOCH₃(84181-11-3)

Safety Data

• Hazardous Substances Data: 84181-11-3(Hazardous Substances Data)

Upstream product

• 6156-78-1 manganese (II) acetate tetrahydrate 

Downstream Products

• 89653-24-7 acetoneazido[tetra(p-tolyl)porphinato]manganese(III) 
• 84206-81-5 nitridomanganese(V) meso-tetrakis(4-methylphenyl)porphyrinate 

Relevant articles and documents

Metal Complexes with Tetrapyrrole Ligands, XXVIII. Mononuclear Nitridomanganese(V) Porphyrins: the First Manganese Nitrogen Triple Bonds

The first complexes containing a manganese-nitrogen triple bond, nitrido(octaethylporphinato)manganese(V) and nitridomanganese(V) , are prepared by hypochlorite oxidation of the corresponding methoxomanganese(III) porphyrins, Mn(OEP)OMe and Mn(TTP)OMe, in the presence of ammonia.The red, pentacoordinated, diamagnetic species are identified by UV/VIS-, IR-, 1H NMR, and mass spectra.While the isoelectronic oxochromium(IV) or oxomolybdenum(IV) porphyrins behave as weak oxidants or reductants, respectively, the nitridomanganese(V) unit in the square pyramidal environment is chemically remarkably stable. - Key words: Manganese Porphyrins, Nitridomanganese Complexes, Metal Nitrogen Triple Bonds