84257-36-3

Basic information

• Product Name: Benzenamine, N-(cyclopentylmethyl)-
• Synonyms: cyclopentylmethyl anilide;N-cyclopentylmethylaniline
• CAS NO: 84257-36-3
• Molecular Formula: C12H17N
• Molecular Weight: 175.274
• Mol File: 84257-36-3.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(cyclopentylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(cyclopentylmethyl)-(84257-36-3)
• EPA Substance Registry System: Benzenamine, N-(cyclopentylmethyl)-(84257-36-3)

Safety Data

• Hazardous Substances Data: 84257-36-3(Hazardous Substances Data)

Upstream product

• 936-52-7 1-(N-morpholino)cyclopent-1-ene 
• 103-72-0 phenyl isothiocyanate 
• 872-53-7 cyclopentanealdehyde 
• 98-95-3 nitrobenzene 
• 62-53-3 aniline 
• 3637-61-4 1-amino-cyclopentanemethanol 
• 2325-27-1 N-phenyltriphenyliminophosphorane 
• 103-84-4 Acetanilid 
• 621-06-7 2,N-diphenylacetamide 
• 93-98-1 N-phenyl benzoyl amide 
• 3400-45-1 cyclopentanecarboxylic acid 
• 142-29-0 cyclopentene 
• 100-61-8 N-methylaniline 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

Continuous flow heterogeneous catalytic reductive aminations under aqueous micellar conditions enabled by an oscillatory plug flow reactor

Despite the fact that continuous flow processing exhibits well-established technical advances, aqueous micellar chemistry, a field that has proven extremely useful in shifting organic synthesis to sustainable water-based media, has mostly been explored under conventional batch-based conditions. This is particularly because of the fact that the reliable handling of slurries and suspensions in flow has been considered as a significant technical challenge. Herein, we demonstrate that the strategic application of an oscillatory plug flow reactor enables heterogeneous catalytic reductive aminations in aqueous micellar media enhancing mass transport and facilitating process simplicity, stability and scalability. The micellar flow process enabled a broad range of substrates, including amino acid derivatives, to be successfully transformed under reasonably mild conditions utilizing only very low amounts of Pd/C as a readily available heterogeneous catalyst. The preparative capabilities of the process along with the recyclability of the heterogenous catalyst and the aqueous reaction media were also demonstrated. This journal is

Direct electrochemical reductive amination between aldehydes and amines with a H/D-donor solvent

A novel electrochemical synthesis protocol has been achieved for reductive amination between aldehydes and amines in undivided cells at room temperature. Under metal-free and external-reductant-free electrolysis conditions, various important secondary amine products are obtained in moderate-to-high yields. Deuterium-labeling experiments have demonstrated that low-toxicity DMSO acts both as a solvent and a H-donor in the reaction. On this basis, various deuterium-labeled products with good-to-excellent D-incorporation have been synthesized by using DMSO-d6 as a solvent. Furthermore, a molecule with GR-antagonistic activity has been synthesized through further sulfonylation.

GROUP 5 METAL COMPLEXES FOR PRODUCING AMINE-FUNTIONALIZED POLYOLEFINS

This application pertains to group 5 metal complexes having the structure of Formula I: and their potential utility in catalyzing amination of polyolefins having alkene groups.amine-