84275-45-6

Basic information

• Product Name: Ethanone, 2-(acetyloxy)-1,2-diphenyl-, (R)-
• CAS NO: 84275-45-6
• Molecular Formula: C16H14O3
• Molecular Weight: 254.285
• Mol File: 84275-45-6.mol
• Article Data: 87

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(acetyloxy)-1,2-diphenyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(acetyloxy)-1,2-diphenyl-, (R)-(84275-45-6)
• EPA Substance Registry System: Ethanone, 2-(acetyloxy)-1,2-diphenyl-, (R)-(84275-45-6)

Safety Data

• Hazardous Substances Data: 84275-45-6(Hazardous Substances Data)

Upstream product

• 127-08-2 potassium acetate 
• 108-24-7 acetic anhydride 
• 1484-50-0 desyl bromide 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 21240-34-6 4,5-diphenyl-1,3-dioxol-2-one 
• 5344-88-7 benzil monohydrazone 
• 34544-89-3 (E,Z)-α-Acetoxystilbene 
• 13892-81-4 (Z)-1-(acetoxy)-1,2-diphenylethylene 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 26205-39-0 1,2-diphenyl-2-(trimethylsilyloxy)ethanone 
• 62796-78-5 1-acetyl-2,3-dihydro-5,7-dinitroindole 
• 506-96-7 Acetyl bromide 
• 20736-40-7 2-(benzyloxy)-1,2-diphenylethanone 
• 108-05-4 vinyl acetate 

Downstream Products

• 14224-99-8 2-methyl-4,5-diphenyloxazole 
• 2818-82-8 2-methyl-4,5-diphenyl-1H-imidazole 
• 981-24-8 1,1,2,2-tetraphenyl-ethanol 
• 35855-69-7 (E)-O,O'-diacetyl-1,2-diphenylethen-1,2-diol 
• 18076-30-7 3,4,5-triphenylpyrazole 
• 5773-56-8 1,2-Diphenylethanol 
• 5928-66-5 (R)-benzoin 
• 93-58-3 benzoic acid methyl ester 
• 451-40-1 phenyl benzyl ketone 
• 29127-98-8 1-(2-Diazo-1,2-diphenyl-ethanesulfonyl)-4-methyl-benzene 
• 29119-40-2 (E)-(1-tosylethene-1,2-diyl)dibenzene 
• 29119-40-2 α-p-Toluolsulfonyl-trans-stilben 
• 29127-96-6 p-Toluolsulfonylazostilben 
• 5172-07-6 Desoxybenzoin-methylhydrazon 

Relevant articles and documents

Noncross-linked polystyrene nanoencapsulation of ferric chloride: A novel and reusable heterogeneous macromolecular Lewis acid catalyst toward selective acetylation of alcohols, phenols, amines, and thiols

Ferric chloride has been successfully nanoencapsulated for the first time on a non-cross-linked polystyrene matrix as the shell material via the coacervation technique. The resulting polystyrene nanoencapsulated ferric chloride was used as a novel and rec

Hypervalent Iodine(III)-Catalysed Enantioselective α-Acetoxylation of Ketones

An enantioselective catalytic synthesis of α-acetoxylated ketones through I(I)/I(III) catalysis using a resorcinol/lactamide-based chiral iodoarene is reported. Catalyst turnover by in situ generation of the active iodine(III) derivative is achieved by oxidation with mCPBA in the presence of acetic acid. The prior transformation of ketones to easily accessible acetyl enol ethers is beneficial and yields up to 97 percent with enantioselectivities up to 88 percent ee are obtained using only low catalyst loadings of only 5 mol percent under mild reaction conditions.

Synthesis of task-specific imidazolium ionic liquid as an efficient catalyst in acetylation of alcohols, phenols, and amines

Herein, we report the synthesis of task-specific amino-functionalized imidazolium ionic liquid, acetate1-(2-tert-butoxycarbonylamino-ethyl)-3-methyl-3H-imidazol-1-ium; (Boc-NH-EMIM.OAc), as an efficient catalyst for the acetylation of alcohols, phenols, and amines in the presence of acetic anhydride (acetylating reagent). Remarkably, acetic anhydride in the presence of 10?molpercent of catalyst (Boc-NH-EMIM.OAc) under solvent-free conditions showed excellent acetylation activity in shorter duration of time. On the basis of this, a general procedure for acetylation of alcohols, phenols, and amines has been developed. The ionic liquid (Boc-NH-EMIM.OAc) can be readily recovered and reused successfully up to four consecutive cycles without any significant loss of its catalytic activity. We have been able to show that this acetylating method has many advantages. It gives high yields, takes shorter time, and develops the possibility of benign environmental-friendly process.