843615-09-8

Basic information

• Product Name: [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphinyl)-
• CAS NO: 843615-09-8
• Molecular Formula: C24H19O2P
• Molecular Weight: 370.387
• Mol File: 843615-09-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphinyl)-(843615-09-8)
• EPA Substance Registry System: [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphinyl)-(843615-09-8)

Safety Data

• Hazardous Substances Data: 843615-09-8(Hazardous Substances Data)

Upstream product

• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 1707-03-5 diphenyl-phosphinic acid 
• 89466-08-0 2-hydroxyphenyl boronic acid 
• 98-80-6 phenylboronic acid 
• 583-55-1 1-Bromo-2-iodobenzene 
• 1079-66-9 chloro-diphenylphosphine 
• 1942-82-1 [1,1′-biphenyl]-2-yldimethylphosphine oxide 
• 2052-07-5 2-Bromobiphenyl 
• 13885-09-1 [1,1′-biphenyl]-2-yldiphenylphosphane 
• 88652-74-8 (2-bromophenyl)diphenylphosphine oxide 
• 4559-70-0 Diphenylphosphine oxide 
• 90-43-7 2-Phenylphenol 
• 22749-43-5 p-chlorodibenzo[c.e][1,2]oxaphosphorine 
• 17763-95-0 2,2'-bis-<<(trifluoromethyl)sulfonyl>oxy>biphenyl 

Downstream Products

• 402822-67-7 2-(diphenylphosphinyl)-2'-methoxyl-1,1'-biphenyl 
• 155566-49-7 (+/-)-2-(diphenylphosphinyo)-2'-<<(trifluoromethyl)sulfonyl>oxy>biphenyl 
• 904887-88-3 (S)-2-(2'-(diphenylphosphoryl)biphenyl-2-yl)-4-isopropyl-4,5-dihydrooxazole 
• 904888-01-3 (S)-4-tert-butyl-2-(2'-(diphenylphosphoryl)biphenyl-2-yl)-4,5-dihydrooxazole 
• 904887-85-0 (S)-2'-(diphenylphosphoryl)-N-(1-hydroxy-3-methylbutan-2-yl)biphenyl-2-carboxamide 
• 904887-98-5 (S)-2'-(diphenylphosphoryl)-N-(1-hydroxy-3,3-dimethylbutan-2-yl)biphenyl-2-carboxamide 
• 1198616-99-7 (S)-2'-(diphenylphosphoryl)-N-(2-hydroxy-1-phenylethyl)biphenyl-2-carboxamide 
• 1198617-03-6 (S)-2-(2'-(diphenylphosphoryl)biphenyl-2-yl)-4-phenyl-4,5-dihydrooxazole 
• 1198791-45-5 (S)-2-(2'-(diphenylphosphino)biphenyl-2-yl)-4-phenyl-4,5-dihydrooxazole 
• 904887-75-8 (S)-2-(2'-(diphenylphosphino)biphenyl-2-yl)-4-isopropyl-4,5-dihydrooxazole 
• 904888-04-6 (S)-4-tert-butyl-2-(2'-(diphenylphosphino)biphenyl-2-yl)-4,5-dihydrooxazole 

Relevant articles and documents

Bifunctional phosphine-catalyzed cross-Rauhut-Currier/Michael/aldol condensation triple domino reaction: Synthesis of functionalized cyclohexenes

A novel bifunctional phosphine-catalyzed reaction was developed. Cross-Rauhut-Currier, Michael and aldol reactions were successfully combined into a domino process. This method offers a powerful approach to the construction of highly substituted cyclohexene skeletons.

Palladium-catalyzed R2(O)P-directed C(sp2)-H activation

In recent years, transition-metal-catalyzed inert C-H bond activation has developed rapidly and is a powerful protocol for the construction of new C-C or C-X bonds and the introduction of new functional groups. Our group has also developed a series of R2(O)P-directed Pd-catalyzed C-H functionalizations involving olefination, hydroxylation, acetoxylation, arylation, and acylation through an uncommon seven-membered cyclo-palladium pretransition state. Unlike previously used directing groups, the R2(O)P group acts as a directing group and is also involved in the construction of P,-hetero-ligands.

Convenient synthesis of tropos phosphine-oxazoline ligands

Tropos phosphine-oxazoline ligands have shown interesting coordination behavior and excellent chiral inducing ability in asymmetry catalysis. Here we present a convenient and economic route for the synthesis of this type of ligands. According to this new route, the ligands with different electronic and steric properties have been prepared successfully.