84445-85-2

Basic information

• Product Name: 1-acetyl-5-methoxybenzimidazolethiol
• Synonyms: 1-acetyl-5-methoxybenzimidazolethiol
• CAS NO: 84445-85-2
• Molecular Weight: 222.268
• Mol File: 84445-85-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-acetyl-5-methoxybenzimidazolethiol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-acetyl-5-methoxybenzimidazolethiol(84445-85-2)
• EPA Substance Registry System: 1-acetyl-5-methoxybenzimidazolethiol(84445-85-2)

Safety Data

• Hazardous Substances Data: 84445-85-2(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 5472-37-7 2'-amino-p-acetanisidide 

Downstream Products

• 79938-46-8 1-acetyl-5-methoxybenzimidazole 

Relevant articles and documents

Synthesis of N-Acetylbenzimidazole Derivatives

For the structure determination of thiazolobenzimidazol-3(2H)-one derivatives (2 or 3) they were converted to the corresponding 1-acetylbenzimidazoles (4) by desulfurization.The latter compounds (4) were alternatively prepared by the cyclization of 2-aminoacetanilide derivatives (5) with CS2 in dimethylformamide (DMF), followed by desulfurization with Raney Ni.However, the reactions of 5 with ethyl orthoformate/H2SO4 in DMF gave a mixture of 4 and its acetyl-rearranged product (7).Keywords-acetyl group; rearrangement; thiazolobenzimidazol-3(2H)-one; N-acetylbenzimidazoles; ethyl orthoformate; carbon disulfide; desulfurization