84563-54-2

Basic information

• Product Name: BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE
• Synonyms: BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE;BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLUOROMETHANESULFONATE;Iodonium,bis[4-(1,1-dimethylethyl)phenyl]-,saltwithtrifluoromethanesulfonicacid(1:1);Iodonium,bis[4-(1,1-dimethylethyl) phenyl]- , salt with trifluoromethanesulfonic acid bis(4-tert-butylphenyl)iodonium triflate;Bis(4-tert-butylphenyl)iodoniuM trifluoroMethanesulfonate, Electronic grade, 99+% (Metals basis);Bis(p-tert-butylphenyl)iodonium triflate;Bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate;Di(4-tert-butylphenyl)iodonium triflate
• CAS NO: 84563-54-2
• Molecular Formula: CF₃O₃S*C₂₀H₂₆I
• Molecular Weight: 542.39
• Product Categories: Diphenyliodonium Compounds;Functional Materials;Iodonium Sulfonium & Oxonium Compounds;Photopolymerization Initiators
• Mol File: 84563-54-2.mol
• Article Data: 32

Chemical Properties

• Melting Point: 237 °C(lit.)
• Appearance: /
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility: ethyl lactate: ~25%
• CAS DataBase Reference: BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE(84563-54-2)
• EPA Substance Registry System: BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE(84563-54-2)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 36/37/39-26
• RIDADR: 3261
• WGK Germany: 3
• Hazardous Substances Data: 84563-54-2(Hazardous Substances Data)

Usage

Chemical Properties

light yellow crystalline powder

InChI:InChI=1/C20H26I.CHF3O3S/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;2-1(3,4)8(5,6)7/h7-14H,1-6H3;(H,5,6,7)/q+1;/p-1

Upstream product

• 253185-03-4 tert-butylbenzene 
• 1493-13-6 trifluorormethanesulfonic acid 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 35895-70-6 tetrabutylammonium trifluoromethylsulfonate 
• 123324-71-0 p-tert-butylphenylboronic acid 
• 120464-15-5 4-tert-butyl(diacetoxyiodo)benzene 

Downstream Products

• 1151782-18-1 (E)-1-(tert-butyl)-4-(3,3-dimethylbut-1-en-1-yl)benzene 
• 1374007-21-2 N-(4-(tert-butyl)phenyl)-S,S-dimethylsulfoximine 
• 1374007-20-1 N-(4-(tert-butyl)phenyl)-S-methyl-S-(4-methylphenyl)-sulfoximine 
• 1392826-96-8 (E)-3-(4-tert-butylphenyl)-2-propen-1-ol acetate 
• 1233691-86-5 1-(4-(tert-butyl)phenyl)naphthalene 
• 5331-28-2 1-tert-butyl-4-phenoxybenzene 
• 946-41-8 2-((4-(tert-butyl)phenyl)thio)ethanol 
• 5851-38-7 3-((4-(tert-butyl)phenyl)thio)propan-1-ol 
• 1416908-56-9 5-(4-(tert-butyl)phenyl)-1-(phenylsulfonyl)-1,2,3,4-tetrahydropyridine 
• 115933-40-9 1-methyl-2-(4-(tert-butyl)phenyl)-1H-pyrrole 
• 1449307-67-8 4-(tert-butyl)-2-(4-methylpyridin-1-ium-1-yl)phenolate 
• 1449307-71-4 4-(tert-butyl)-2-(3-methylpyridin-1-ium-1-yl)phenolate 
• 1448632-01-6 (4-(tert-butyl)phenyl)diphenylphosphine oxide 
• 253185-03-4 tert-butylbenzene 

Relevant articles and documents

Direct Copper-Catalyzed C-3 Arylation of Diphenylphosphine Oxide Indoles

We have developed a simple and effective method for the C-3 arylation of phosphorus-containing indole compounds in the presence of CuI under mild conditions. This reaction provides a reliable method for the modification of ligands.

N1- and N3-Arylations of Hydantoins Employing Diaryliodonium Salts via Copper(I) Catalysis at Room Temperature

Copper(I)-catalyzed N-arylation (both N1- and N3-) of hydantoins with diaryliodonium salts as aryl partners at room temperature is reported. The transformation allows diverse scopes on both hydantoins and diaryliodonium salts deliver

Palladium(ii)-catalyzed stereoselective synthesis of: C-glycosides from glycals with diaryliodonium salts

An efficient palladium(ii) mediated C-glycosylation of glycals with diaryliodonium salts is described, providing a new strategy for the synthesis of 2,3-dideoxy C-Aryl glycosides with excellent stereoselectivity. The C-glycosylation of a diverse range of