84574-18-5Relevant articles and documents
AN IMPORTANT ROLE PLAYED BY DIANIONES IN THE HIGHLY EFFICIENT MACROCYCLE FORMATION BY AN INTRAMOLECULAR ALKYLATION METHOD: APPLICATION TO THE SYNTHESIS OF ZEARALENONE
Takahashi, Takashi,Nagashima, Toshiharu,Ikeda, Hiroshi,Tsuji, Jiro
, p. 4361 - 4364 (2007/10/02)
A new synthetic method for macrolides based on intramolecular alkylation of dianions, generated from phenylthiomethyl group and protected cyanohydrin, is reported.The use of dianions for the cyclization has several characteristic features; (1) Control of