84622-64-0

Basic information

• Product Name: N-<2-(Triphenylphosphonio)ethoxycarbonyl>valin-chlorid
• CAS NO: 84622-64-0
• Molecular Weight: 485.947
• Mol File: 84622-64-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-<2-(Triphenylphosphonio)ethoxycarbonyl>valin-chlorid(CAS DataBase Reference)
• NIST Chemistry Reference: N-<2-(Triphenylphosphonio)ethoxycarbonyl>valin-chlorid(84622-64-0)
• EPA Substance Registry System: N-<2-(Triphenylphosphonio)ethoxycarbonyl>valin-chlorid(84622-64-0)

Safety Data

• Hazardous Substances Data: 84622-64-0(Hazardous Substances Data)

Upstream product

• 72-18-4 L-valine 
• 7364-44-5 N,O-bis(trimethylsilyl)-L-valine 

Downstream Products

• 82414-81-1 hydroxyisovaleroylvalyl>-N-methylleucin-tert-butylester-chlorid 
• 84569-82-4 hydroxyisovaleroylvalyl>leucin-tert-butylester-chlorid 
• 84569-83-5 lactoylvalyl>-N-methylleucin-tert-butylester-chlorid 
• 84569-84-6 lactoylvalyl>leucin-tert-butylester-chlorid 
• 84569-85-7 [2-((S)-1-{(S)-1-[((S)-1-Carboxy-3-methyl-butyl)-methyl-carbamoyl]-2-methyl-propylcarbamoyl}-2-methyl-propoxycarbonyloxy)-ethyl]-triphenyl-phosphonium; chloride 
• 84569-86-8 (2-{(S)-1-[(S)-1-((S)-1-Carboxy-3-methyl-butylcarbamoyl)-2-methyl-propylcarbamoyl]-2-methyl-propoxycarbonyloxy}-ethyl)-triphenyl-phosphonium; chloride 
• 84569-87-9 [2-((S)-1-{(S)-1-[((S)-1-Carboxy-3-methyl-butyl)-methyl-carbamoyl]-2-methyl-propylcarbamoyl}-ethoxycarbonyloxy)-ethyl]-triphenyl-phosphonium; chloride 
• 84569-88-0 (2-{(S)-1-[(S)-1-((S)-1-Carboxy-3-methyl-butylcarbamoyl)-2-methyl-propylcarbamoyl]-ethoxycarbonyloxy}-ethyl)-triphenyl-phosphonium; chloride 
• 84569-74-4 valyl>phenylalanin-tert-butylester-chlorid 
• 82414-76-4 valyl>-N-methylleucin-tert-butylester-chlorid 
• 84569-73-3 valyl>isoleucin-tert-butylester-chlorid 
• 84569-72-2 valyl>leucin-tert-butylester-chlorid 
• 84569-77-7 valyl>sarkosin-tert-butylester-chlorid 
• 84569-76-6 valyl>alanin-tert-butylester-chlorid 

Relevant articles and documents

Syntheses of Sterically Hindered Peptides and Depsipeptides by Means of an Acid Chloride Procedure with 2-Phosphonioethoxycarbonyl (Peoc) Amino Acids and Hydroxy Acids

2-(Triphenylphosphonio)ethoxycarbonyl (Peoc) amino acids 1 and hydroxy acids 5 are converted by treatment with oxalyl chloride into the corresponding acid chlorides 2 and 6 which are stable at room temperature.Sterically hindered amide bonds, for instance